diff --git "a/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/QaZQ1Ndvo1g_raw.json" "b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/QaZQ1Ndvo1g_raw.json"
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+{"segments": [{"id": 1, "seek": 3334, "start": 7.36, "end": 33.34, "text": "بسم الله الرحمن الرحيم اتكلمنا المرة الماضية في موضوع ال ethers بشكل أساسي تسمية ال ethers وخواصها اليوم بنستمر في تناول هذا الموضوع هنتكلم على تحضير ال ethers و بعض تفاعلاتها زي التوسع في هذا المجال", "tokens": [3555, 38251, 21984, 34892, 5016, 27842, 34892, 5016, 32640, 1975, 2655, 4117, 19528, 8315, 9673, 25720, 9673, 46958, 10632, 8978, 3714, 2407, 11242, 45367, 2423, 6468, 433, 4724, 8592, 28820, 5551, 3794, 32277, 1829, 6055, 38251, 10632, 2423, 6468, 433, 4032, 9778, 2407, 33546, 11296, 45595, 20498, 44945, 14851, 29973, 8978, 6055, 8315, 12610, 23758, 9673, 2407, 11242, 45367, 8032, 29399, 4117, 19528, 15844, 6055, 5016, 11242, 13546, 2423, 6468, 433, 4032, 45030, 11242, 6055, 5172, 995, 30241, 9307, 11296, 30767, 1829, 16712, 41779, 3615, 8978, 23758, 9673, 7435, 6027], "avg_logprob": -0.10533997154497839, "compression_ratio": 1.875, "no_speech_prob": 3.5762786865234375e-07, "words": [{"start": 7.36, 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نوعين ممكن ال ether تكون symmetric بمعنى مجموعتين ال R اللي موجودات زي بعض يعني لما نقول اثل اثل هذا symmetric ether", "tokens": [6027, 7649, 7251, 20498, 19446, 4724, 1829, 7435, 1829, 24793, 1975, 1829, 37096, 39894, 30544, 14407, 6225, 9640, 5172, 9957, 16472, 2423, 37096, 6055, 4587, 38251, 2423, 7578, 8717, 45367, 9957, 3714, 43020, 2423, 37096, 6055, 30544, 32330, 4724, 2304, 3615, 1863, 7578, 3714, 7435, 2304, 2407, 34268, 9957, 2423, 497, 13672, 1829, 3714, 29245, 23328, 9307, 30767, 1829, 45030, 11242, 37495, 22653, 5296, 15042, 8717, 39648, 1975, 12984, 1211, 1975, 12984, 1211, 23758, 32330, 37096], "avg_logprob": -0.2883522758236179, "compression_ratio": 1.6589595375722543, "no_speech_prob": 0.0, "words": [{"start": 33.95, "end": 34.45, "word": "الان", "probability": 0.703857421875}, {"start": 34.45, "end": 34.87, "word": " يوم", "probability": 0.769775390625}, {"start": 34.87, "end": 35.01, "word": " ما", "probability": 0.767578125}, {"start": 35.01, "end": 35.53, "word": " 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لما", "probability": 0.75927734375}, {"start": 52.73, "end": 53.07, "word": " نقول", "probability": 0.963134765625}, {"start": 53.07, "end": 53.59, "word": " اثل", "probability": 0.6256917317708334}, {"start": 53.59, "end": 54.13, "word": " اثل", "probability": 0.97412109375}, {"start": 54.13, "end": 54.47, "word": " هذا", "probability": 0.5}, {"start": 54.47, "end": 54.97, "word": " symmetric", "probability": 0.488037109375}, {"start": 54.97, "end": 55.43, "word": " ether", "probability": 0.72216796875}], "temperature": 1.0}, {"id": 3, "seek": 7189, "start": 56.19, "end": 71.89, "text": "مثل مثل فنل فنل كل هذه عبارة عن symmetrical ethers وممكن ال ethers تكون unsymmetrical بمعنى يكون في عند مثلا اثل مع مثل او", "tokens": [2304, 12984, 1211, 50113, 1211, 6156, 1863, 1211, 6156, 1863, 1211, 28242, 29538, 6225, 3555, 9640, 3660, 18871, 40360, 6468, 433, 4032, 2304, 43020, 2423, 6468, 433, 6055, 30544, 2693, 32497, 32283, 4724, 2304, 3615, 1863, 7578, 7251, 30544, 8978, 43242, 50113, 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sulfuric acid على 140 درجة مئوية بيعطينا ال diethyl ether واضح؟", "tokens": [6027, 39184, 40360, 6468, 433, 23032, 16572, 28671, 6055, 5016, 11242, 13546, 16095, 8608, 3224, 37977, 4032, 2304, 43020, 3714, 43500, 25894, 8315, 6225, 43042, 995, 5551, 12984, 1863, 16606, 6055, 4117, 19528, 8315, 18871, 16247, 1211, 4117, 9957, 9307, 11933, 15730, 5551, 9778, 3215, 8315, 33251, 5016, 12610, 46952, 9778, 8315, 3224, 5296, 5016, 2288, 9640, 3660, 3714, 24401, 41891, 8978, 49610, 23328, 11331, 10943, 11242, 4724, 40228, 9566, 1829, 8315, 2423, 37096, 37495, 22653, 50113, 15040, 2423, 6339, 3495, 75, 37096, 11933, 15730, 1975, 5016, 8315, 5551, 9778, 3215, 8315, 2423, 43150, 20449, 33831, 299, 8258, 15844, 21548, 11778, 47341, 3660, 3714, 19986, 2407, 10632, 4724, 40228, 9566, 1829, 8315, 2423, 6339, 3495, 75, 37096, 4032, 46958, 5016, 22807], "avg_logprob": -0.1639344230538509, "compression_ratio": 1.6795366795366795, "no_speech_prob": 2.384185791015625e-07, "words": [{"start": 91.63, "end": 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0.64794921875}, {"start": 348.29, "end": 348.83, "word": " معادلة", "probability": 0.9488932291666666}, {"start": 348.83, "end": 349.11, "word": " هيك", "probability": 0.50927734375}, {"start": 349.11, "end": 349.77, "word": " لوحدها", "probability": 0.951171875}, {"start": 349.77, "end": 350.93, "word": " الناتج", "probability": 0.7342122395833334}, {"start": 350.93, "end": 351.11, "word": " اللى", "probability": 0.84375}, {"start": 351.11, "end": 351.41, "word": " صار", "probability": 0.981689453125}, {"start": 351.41, "end": 351.75, "word": " عندى", "probability": 0.935546875}, {"start": 351.75, "end": 352.07, "word": " هنا", "probability": 0.9208984375}, {"start": 352.07, "end": 352.95, "word": " باجب", "probability": 0.779296875}, {"start": 352.95, "end": 353.77, "word": " فعله", "probability": 0.8424479166666666}, {"start": 353.77, "end": 354.45, "word": " مع", "probability": 0.91796875}, {"start": 354.45, "end": 355.37, "word": " RX", "probability": 0.82275390625}, {"start": 355.37, "end": 356.13, "word": " تانية", "probability": 0.95263671875}], "temperature": 1.0}, {"id": 16, "seek": 37644, "start": 356.92, "end": 376.44, "text": "واضح؟ يعني أرجو أنه ما تفهموش هذه المعادلة لأن هذا بيطلع الناتجين لأ هذه معادلة لوحدها أنه انا لو أخدت الethanol مع ال sodium بيطلع له sodium ethoxide صار كل المحلول عبارة عن sodium ethoxide الآن هذا ال sodium ethoxide بنيجي بنضيفه", "tokens": [2407, 46958, 5016, 22807, 37495, 22653, 5551, 47341, 2407, 14739, 3224, 19446, 6055, 5172, 16095, 2407, 8592, 29538, 9673, 3615, 18513, 37977, 5296, 33456, 23758, 4724, 1829, 9566, 1211, 3615, 2423, 8315, 2655, 7435, 9957, 5296, 10721, 29538, 20449, 18513, 37977, 45164, 24401, 11296, 14739, 3224, 1975, 8315, 45164, 5551, 9778, 3215, 2655, 2423, 3293, 282, 401, 20449, 2423, 20265, 4724, 1829, 9566, 1211, 3615, 46740, 20265, 1030, 1289, 34454, 20328, 9640, 28242, 9673, 5016, 1211, 12610, 6225, 3555, 9640, 3660, 18871, 20265, 1030, 1289, 34454, 6024, 48506, 23758, 2423, 20265, 1030, 1289, 34454, 44945, 1829, 7435, 1829, 44945, 11242, 33911, 3224], "avg_logprob": -0.21905340529182582, "compression_ratio": 1.8208955223880596, "no_speech_prob": 8.344650268554688e-07, "words": [{"start": 356.92, "end": 357.72, "word": "واضح؟", "probability": 0.73681640625}, {"start": 357.72, "end": 358.04, "word": " يعني", "probability": 0.82958984375}, {"start": 358.04, "end": 358.34, "word": " أرجو", "probability": 0.5931803385416666}, {"start": 358.34, "end": 358.48, "word": " أنه", "probability": 0.576171875}, {"start": 358.48, "end": 358.56, "word": " ما", "probability": 0.66064453125}, {"start": 358.56, "end": 359.06, "word": " تفهموش", "probability": 0.96083984375}, {"start": 359.06, "end": 359.22, "word": " هذه", "probability": 0.845703125}, {"start": 359.22, "end": 359.72, "word": " المعادلة", "probability": 0.98486328125}, {"start": 359.72, "end": 359.9, "word": " لأن", "probability": 0.5640869140625}, {"start": 359.9, "end": 360.3, "word": " هذا", "probability": 0.81689453125}, {"start": 360.3, "end": 360.9, "word": " بيطلع", "probability": 0.780029296875}, {"start": 360.9, "end": 361.6, "word": " الناتجين", "probability": 0.78603515625}, {"start": 361.6, "end": 362.16, "word": " لأ", "probability": 0.7376708984375}, {"start": 362.16, "end": 362.4, "word": " هذه", "probability": 0.77685546875}, {"start": 362.4, "end": 363.02, "word": " معادلة", "probability": 0.9892578125}, {"start": 363.02, "end": 363.8, "word": " لوحدها", "probability": 0.9495442708333334}, {"start": 363.8, "end": 364.64, "word": " أنه", "probability": 0.691650390625}, {"start": 364.64, "end": 364.82, "word": " انا", "probability": 0.665283203125}, {"start": 364.82, "end": 364.96, "word": " لو", "probability": 0.94189453125}, {"start": 364.96, "end": 365.34, "word": " أخدت", "probability": 0.9691162109375}, {"start": 365.34, "end": 365.88, "word": " الethanol", "probability": 0.726226806640625}, {"start": 365.88, "end": 366.06, "word": " مع", "probability": 0.98388671875}, {"start": 366.06, "end": 366.24, "word": " ال", "probability": 0.8310546875}, {"start": 366.24, "end": 366.6, "word": " sodium", "probability": 0.75146484375}, {"start": 366.6, "end": 367.52, "word": " بيطلع", "probability": 0.9212890625}, {"start": 367.52, "end": 367.8, "word": " له", "probability": 0.56298828125}, {"start": 367.8, "end": 369.04, "word": " sodium", "probability": 0.73583984375}, {"start": 369.04, "end": 369.84, "word": " ethoxide", "probability": 0.8974609375}, {"start": 369.84, "end": 370.14, "word": " صار", "probability": 0.8115234375}, {"start": 370.14, "end": 370.36, "word": " كل", "probability": 0.98388671875}, {"start": 370.36, "end": 370.9, "word": " المحلول", "probability": 0.993896484375}, {"start": 370.9, "end": 371.34, "word": " عبارة", "probability": 0.993408203125}, {"start": 371.34, "end": 371.62, "word": " عن", "probability": 0.998046875}, {"start": 371.62, "end": 372.36, "word": " sodium", "probability": 0.732421875}, {"start": 372.36, "end": 373.08, "word": " ethoxide", "probability": 0.9169921875}, {"start": 373.08, "end": 373.62, "word": " الآن", "probability": 0.56304931640625}, {"start": 373.62, "end": 373.92, "word": " هذا", "probability": 0.97900390625}, {"start": 373.92, "end": 374.06, "word": " ال", "probability": 0.8583984375}, {"start": 374.06, "end": 374.38, "word": " sodium", "probability": 0.9296875}, {"start": 374.38, "end": 375.04, "word": " ethoxide", "probability": 0.9119466145833334}, {"start": 375.04, "end": 375.5, "word": " بنيجي", "probability": 0.8497314453125}, {"start": 375.5, "end": 376.44, "word": " بنضيفه", "probability": 0.915771484375}], "temperature": 1.0}, {"id": 17, "seek": 39415, "start": 377.31, "end": 394.15, "text": "أو من فعله مرة تانية مع R' X أي R تانية نفترض مثلا CH3CL الـ RO- هذ�� بتيجي بتعمل عملية إبدال على الـ RX بتهاجم هيك و بتطرد الـ X", "tokens": [10721, 2407, 9154, 6156, 30241, 3224, 3714, 25720, 6055, 7649, 10632, 20449, 497, 6, 1783, 36632, 497, 6055, 7649, 10632, 8717, 5172, 2655, 43042, 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X", "probability": 0.62255859375}, {"start": 381.71, "end": 382.03, "word": " أي", "probability": 0.66748046875}, {"start": 382.03, "end": 382.33, "word": " R", "probability": 0.87744140625}, {"start": 382.33, "end": 382.79, "word": " تانية", "probability": 0.9654947916666666}, {"start": 382.79, "end": 384.21, "word": " نفترض", "probability": 0.83740234375}, {"start": 384.21, "end": 384.75, "word": " مثلا", "probability": 0.816650390625}, {"start": 384.75, "end": 386.77, "word": " CH3CL", "probability": 0.8082682291666666}, {"start": 386.77, "end": 388.17, "word": " الـ", "probability": 0.55419921875}, {"start": 388.17, "end": 388.57, "word": " RO", "probability": 0.32421875}, {"start": 388.57, "end": 389.03, "word": "-", "probability": 0.467529296875}, {"start": 389.03, "end": 389.63, "word": " هذه", "probability": 0.39794921875}, {"start": 389.63, "end": 390.23, "word": " بتيجي", "probability": 0.67742919921875}, {"start": 390.23, "end": 390.79, "word": " بتعمل", "probability": 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الأساسي لمُركّبات الـRX هو الـ Substitution واخدنا أنها ممكن تتم بـ Sn1 وممكن تتم بـ Sn2 ميكانيزم، واضحة؟ فكأنه أنا صار عندي هلأ بالتأكيد ر أو ماينوس هاجمت على R' X طلعت الـ X فبصير عندي ر أو ر ناتج واحد فقط ناتج واحد فقط", "tokens": [2407, 47283, 3215, 8315, 14739, 16712, 5172, 995, 30241, 16247, 3794, 32277, 1829, 32767, 10859, 31747, 11703, 3555, 9307, 2423, 39184, 49, 55, 31439, 2423, 39184, 42090, 6518, 4032, 47283, 3215, 8315, 14739, 11296, 3714, 43020, 6055, 39237, 4724, 39184, 9264, 16, 4032, 2304, 43020, 6055, 39237, 4724, 39184, 9264, 17, 3714, 1829, 41361, 1829, 11622, 2304, 12399, 4032, 46958, 5016, 3660, 22807, 6156, 4117, 33456, 3224, 41850, 20328, 9640, 43242, 1829, 8032, 1211, 10721, 20666, 2655, 10721, 4117, 25708, 12602, 34051, 19446, 9957, 41779, 8032, 26108, 2304, 2655, 15844, 497, 6, 1783, 23032, 1211, 34268, 2423, 39184, 1783, 6156, 3555, 9381, 13546, 43242, 1829, 12602, 34051, 12602, 8717, 9307, 7435, 36764, 24401, 6156, 47432, 8717, 9307, 7435, 36764, 24401, 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"probability": 0.6158854166666666}, {"start": 415.59, "end": 415.81, "word": " الـ", "probability": 0.76513671875}, {"start": 415.81, "end": 416.01, "word": " X", "probability": 0.74609375}, {"start": 416.01, "end": 416.45, "word": " فبصير", "probability": 0.7861328125}, {"start": 416.45, "end": 416.77, "word": " عندي", "probability": 0.78662109375}, {"start": 416.77, "end": 417.03, "word": " ر", "probability": 0.36474609375}, {"start": 417.03, "end": 417.25, "word": " أو", "probability": 0.94287109375}, {"start": 417.25, "end": 417.59, "word": " ر", "probability": 0.548828125}, {"start": 417.59, "end": 418.69, "word": " ناتج", "probability": 0.94580078125}, {"start": 418.69, "end": 419.35, "word": " واحد", "probability": 0.99072265625}, {"start": 419.35, "end": 419.91, "word": " فقط", "probability": 0.994140625}, {"start": 419.91, "end": 420.67, "word": " ناتج", "probability": 0.8465169270833334}, {"start": 420.67, "end": 421.19, "word": " واحد", "probability": 0.995849609375}, 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{"start": 804.09, "end": 804.43, "word": " ممكن", "probability": 0.959228515625}, {"start": 804.43, "end": 804.73, "word": " ناخد", "probability": 0.9947916666666666}, {"start": 804.73, "end": 805.45, "word": " محاضرتين", "probability": 0.9734375}, {"start": 805.45, "end": 805.65, "word": " أو", "probability": 0.81982421875}, {"start": 805.65, "end": 806.29, "word": " تلاتة", "probability": 0.9755859375}, {"start": 806.29, "end": 807.09, "word": " لما", "probability": 0.872802734375}, {"start": 807.09, "end": 807.53, "word": " حكينا", "probability": 0.98828125}, {"start": 807.53, "end": 807.75, "word": " على", "probability": 0.81689453125}, {"start": 807.75, "end": 807.91, "word": " ال", "probability": 0.9775390625}, {"start": 807.91, "end": 808.85, "word": " alkenes", "probability": 0.6776529947916666}], "temperature": 1.0}, {"id": 35, "seek": 82925, "start": 809.85, "end": 829.25, "text": "تفاعلات الإضافة والـ Palmer وما إلى ذلك كانت قصة، بظبط ولا لا؟ لكن لما بنحكي على الـEthers، 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"word": " اليتيم", "probability": 0.76025390625}], "temperature": 1.0}, {"id": 36, "seek": 85945, "start": 830.05, "end": 859.45, "text": "مع حامض قوى مثل الـ HI بس حامض قوى مثل الـ HI بكسرهم إذا تفاعلهم تفاعل إكليفج إيش يعني إكليفج؟ تكسير إكليفج reaction يعني إن أكسر المركب إلى نصين طيب كيف مثلا لو أخدنا هذا ال ether الفيرل O CH2 CH3 نرجع لنفس ال ether الآن هذا لما نيجي الفعل مع HI ال I تعتبر", "tokens": [2304, 3615, 11331, 10943, 11242, 12174, 2407, 7578, 50113, 1211, 2423, 39184, 44376, 4724, 3794, 11331, 10943, 11242, 12174, 2407, 7578, 50113, 1211, 2423, 39184, 44376, 4724, 4117, 3794, 2288, 16095, 11933, 15730, 6055, 5172, 995, 30241, 16095, 6055, 5172, 995, 30241, 11933, 4117, 20292, 5172, 7435, 11933, 1829, 8592, 37495, 22653, 11933, 4117, 20292, 5172, 7435, 22807, 6055, 4117, 3794, 13546, 11933, 4117, 20292, 5172, 7435, 5480, 37495, 22653, 36145, 5551, 4117, 3794, 2288, 9673, 31747, 3555, 30731, 8717, 9381, 9957, 23032, 1829, 3555, 9122, 33911, 50113, 15040, 45164, 5551, 9778, 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"seek": 90296, "start": 877.58, "end": 902.96, "text": "وبتكسر هذه كأنه عملت عكس التفاعل السابق كأنه عملت عكس التفاعل السابق بتصير أدفين الـ O minus وبعدين بتاخد الـ H plus من اللي كانت مع الـ I زائد CH3CH2I إذا هنا تكسير هذا ال ether بالـ HI أعطاني الكهول زائد الكلهلين لاحظوا هو عكس", "tokens": [37746, 2655, 4117, 3794, 2288, 29538, 9122, 33456, 3224, 6225, 42213, 2655, 6225, 4117, 3794, 16712, 5172, 995, 30241, 21136, 16758, 4587, 9122, 33456, 3224, 6225, 42213, 2655, 6225, 4117, 3794, 16712, 5172, 995, 30241, 21136, 16758, 4587, 39894, 9381, 13546, 5551, 3215, 5172, 9957, 2423, 39184, 422, 3175, 46599, 22488, 9957, 39894, 47283, 3215, 2423, 39184, 389, 1804, 9154, 13672, 1829, 25961, 2655, 20449, 2423, 39184, 286, 30767, 16373, 3215, 5995, 18, 5462, 17, 40, 11933, 15730, 34105, 6055, 4117, 3794, 13546, 23758, 2423, 37096, 20666, 39184, 44376, 5551, 3615, 9566, 7649, 1829, 33251, 3224, 12610, 30767, 16373, 3215, 2423, 28820, 3224, 1211, 9957, 20193, 5016, 19913, 14407, 31439, 6225, 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كتير لأنه له تطبيقات في التحضيرات العضوية وانا بتهيأها ليه؟ انه احنا أخدنا", "tokens": [3224, 15730, 2423, 39184, 16489, 347, 1929, 13672, 1829, 31439, 5551, 3555, 3794, 9566, 10295, 66, 1050, 38636, 44381, 23758, 10295, 66, 1050, 38636, 3714, 16095, 9122, 2655, 13546, 5296, 33456, 3224, 46740, 6055, 9566, 21292, 4587, 9307, 8978, 16712, 5016, 11242, 13546, 9307, 18863, 11242, 2407, 10632, 4032, 7649, 995, 39894, 3224, 1829, 10721, 11296, 32239, 3224, 22807, 16472, 3224, 1975, 5016, 8315, 5551, 9778, 3215, 8315], "avg_logprob": -0.23075181504954462, "compression_ratio": 1.3902439024390243, "no_speech_prob": 1.0728836059570312e-06, "words": [{"start": 1491.07, "end": 1491.59, "word": "هذا", "probability": 0.834228515625}, {"start": 1491.59, "end": 1491.87, "word": " الـ", "probability": 0.3358154296875}, {"start": 1491.87, "end": 1492.53, "word": " Oxirane", "probability": 0.635498046875}, {"start": 1492.53, "end": 1492.77, "word": " اللي", "probability": 0.5186767578125}, {"start": 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1700.63, "end": 1701.37, "word": " CH2", "probability": 0.92626953125}, {"start": 1701.37, "end": 1701.45, "word": " OH", "probability": 0.93017578125}], "temperature": 1.0}, {"id": 70, "seek": 173147, "start": 1707.97, "end": 1731.47, "text": "تنسوش تحطوا ال O هذي اللي مانسية في الراسي أول مركّب O H طبعا ال cyclic ethers مش بس حلقات ثلاثية ممكن يكونوا موجودين على شكل", "tokens": [2655, 1863, 3794, 2407, 8592, 6055, 5016, 9566, 14407, 2423, 422, 8032, 8848, 1829, 13672, 1829, 3714, 7649, 3794, 10632, 8978, 34892, 32277, 1829, 5551, 12610, 3714, 31747, 11703, 3555, 422, 389, 23032, 3555, 3615, 995, 2423, 38154, 1050, 6468, 433, 37893, 4724, 3794, 11331, 1211, 4587, 9307, 38637, 1211, 5718, 104, 10632, 3714, 43020, 7251, 30544, 14407, 3714, 29245, 23328, 9957, 15844, 13412, 28820], "avg_logprob": -0.2608901488058495, "compression_ratio": 1.3461538461538463, "no_speech_prob": 0.0, "words": [{"start": 1707.97, "end": 1708.47, "word": "تنسوش", "probability": 0.89140625}, {"start": 1708.47, 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