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+{"segments": [{"id": 1, "seek": 3567, "start": 7.73, "end": 35.67, "text": "المحاضرة الماضية بعد ما اتكلمنا عن الـalcohols والتسميتهم والـhydrogen bonding والخواص بدأنا في موضوع كثير مهم في موضوع الـalcohols اللي هو الموضوع الحامضية الـacidity طبعا حكينا احنا شغلة ان الـacidity حسب تعريف لوري برونستيد الـacid بروتون دونر بدو يفقد بروتون", "tokens": [45340, 5016, 46958, 25720, 9673, 46958, 10632, 39182, 19446, 1975, 2655, 4117, 19528, 8315, 18871, 2423, 39184, 304, 7210, 82, 16070, 2655, 38251, 36081, 16095, 16070, 39184, 21591, 7747, 28824, 16070, 9778, 2407, 33546, 47525, 10721, 8315, 8978, 3714, 2407, 11242, 45367, 9122, 12984, 13546, 3714, 16095, 8978, 3714, 2407, 11242, 45367, 2423, 39184, 304, 7210, 82, 13672, 1829, 31439, 9673, 2407, 11242, 45367, 21542, 10943, 11242, 10632, 2423, 39184, 326, 17711, 23032, 3555, 3615, 995, 11331, 4117, 1829, 8315, 1975, 5016, 8315, 13412, 17082, 37977, 16472, 2423, 39184, 326, 17711, 11331, 35457, 37279, 16572, 5172, 5296, 13063, 1829, 4724, 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716.71, "word": " قولنا", "probability": 0.7461751302083334}, {"start": 716.71, "end": 717.37, "word": " ليش", "probability": 0.8505859375}, {"start": 717.37, "end": 717.55, "word": " ال", "probability": 0.56298828125}, {"start": 717.55, "end": 718.07, "word": " tertiary", "probability": 0.902587890625}, {"start": 718.07, "end": 718.91, "word": " carbocation", "probability": 0.920166015625}, {"start": 718.91, "end": 719.15, "word": " is", "probability": 0.80322265625}, {"start": 719.15, "end": 720.03, "word": " stable؟", "probability": 0.692138671875}, {"start": 720.03, "end": 720.65, "word": " لأنه", "probability": 0.7667643229166666}, {"start": 720.65, "end": 721.09, "word": " فيه", "probability": 0.76806640625}], "temperature": 1.0}, {"id": 29, "seek": 73256, "start": 722.62, "end": 732.56, "text": "Electron donating groups مجموعات بتعطي إلكترونات فهذه اللي بتعطي إلكترونات شو بتعمل في positive charge؟ بتقلل؟", "tokens": [36, 1809, 2044, 36686, 3935, 3714, 7435, 2304, 45367, 9307, 39894, 3615, 9566, 1829, 11933, 23275, 2655, 2288, 11536, 9307, 6156, 3224, 24192, 13672, 1829, 39894, 3615, 9566, 1829, 11933, 23275, 2655, 2288, 11536, 9307, 13412, 2407, 39894, 25957, 1211, 8978, 3353, 4602, 22807, 39894, 4587, 1211, 1211, 22807], "avg_logprob": -0.1657812476158142, "compression_ratio": 1.310077519379845, "no_speech_prob": 2.0265579223632812e-06, "words": [{"start": 722.62, "end": 723.38, "word": "Electron", "probability": 0.6670735677083334}, {"start": 723.38, "end": 723.88, "word": " donating", "probability": 0.78076171875}, {"start": 723.88, "end": 724.58, "word": " groups", "probability": 0.91259765625}, {"start": 724.58, "end": 725.26, "word": " مجموعات", "probability": 0.89345703125}, {"start": 725.26, "end": 725.72, "word": " بتعطي", "probability": 0.9329833984375}, {"start": 725.72, "end": 726.58, "word": " إلكترونات", "probability": 0.8638102213541666}, {"start": 726.58, "end": 727.5, "word": " فهذه", "probability": 0.6951497395833334}, {"start": 727.5, 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الإيثانول لأن مرة عندنا electron donation هنا في إعطاء إلكترونات", "tokens": [6027, 39184, 3353, 4602, 4032, 46958, 5016, 22807, 23758, 31439, 13672, 1829, 44945, 38251, 1829, 3224, 31612, 488, 1802, 4032, 13672, 1829, 44945, 36178, 2288, 8978, 3224, 32239, 8592, 2423, 39184, 38726, 29104, 4724, 1829, 35473, 16247, 23275, 2407, 3224, 12610, 11331, 2304, 11242, 36081, 3224, 5551, 4587, 1211, 9154, 33688, 1829, 12984, 7649, 12610, 50113, 15040, 4032, 32239, 8592, 2423, 39184, 36956, 2781, 10780, 3293, 282, 401, 11331, 2304, 11242, 36081, 3224, 5551, 4117, 2655, 2288, 9154, 33688, 1829, 12984, 7649, 12610, 5296, 33456, 3714, 25720, 43242, 8315, 6084, 19724, 34105, 8978, 11933, 3615, 9566, 16606, 11933, 23275, 2655, 2288, 11536, 9307], "avg_logprob": -0.1808894257992506, "compression_ratio": 1.6297872340425532, "no_speech_prob": 2.384185791015625e-07, "words": [{"start": 732.88, "end": 733.24, "word": "الـ", "probability": 0.693603515625}, {"start": 733.24, "end": 733.58, "word": " 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{"start": 747.62, "end": 748.08, "word": " الـ", "probability": 0.851806640625}, {"start": 748.08, "end": 749.24, "word": " trifluoroethanol", "probability": 0.8182373046875}, {"start": 749.24, "end": 749.88, "word": " حمضيته", "probability": 0.99169921875}, {"start": 749.88, "end": 750.22, "word": " أكتر", "probability": 0.9765625}, {"start": 750.22, "end": 750.4, "word": " من", "probability": 0.994140625}, {"start": 750.4, "end": 751.0, "word": " الإيثانول", "probability": 0.97900390625}, {"start": 751.0, "end": 751.52, "word": " لأن", "probability": 0.760498046875}, {"start": 751.52, "end": 751.92, "word": " مرة", "probability": 0.697509765625}, {"start": 751.92, "end": 752.72, "word": " عندنا", "probability": 0.985107421875}, {"start": 752.72, "end": 754.48, "word": " electron", "probability": 0.87841796875}, {"start": 754.48, "end": 755.18, "word": " donation", "probability": 0.9658203125}, {"start": 755.18, "end": 755.58, "word": " هنا", "probability": 0.59375}, {"start": 755.58, 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"word": " زيادة", "probability": 0.9530029296875}, {"start": 759.47, "end": 759.95, "word": " الشحنة", "probability": 0.8277587890625}, {"start": 759.95, "end": 760.11, "word": " هنا", "probability": 0.66845703125}, {"start": 760.11, "end": 760.27, "word": " في", "probability": 0.94140625}, {"start": 760.27, "end": 760.67, "word": " سحب", "probability": 0.9456380208333334}, {"start": 760.67, "end": 761.43, "word": " الإلكترونات", "probability": 0.81787109375}, {"start": 761.43, "end": 761.91, "word": " وبالتالي", "probability": 0.9587890625}, {"start": 761.91, "end": 762.37, "word": " تقليل", "probability": 0.944580078125}, {"start": 762.37, "end": 762.81, "word": " الشحنة", "probability": 0.943115234375}, {"start": 762.81, "end": 762.83, "word": " اللي", "probability": 0.737060546875}, {"start": 762.83, "end": 762.93, "word": " هي", "probability": 0.77880859375}, {"start": 762.93, "end": 763.27, "word": " الشحنة", "probability": 0.984619140625}, {"start": 763.27, "end": 763.57, "word": " أشهر", "probability": 0.79364013671875}, {"start": 763.57, "end": 764.07, "word": " بتكون", "probability": 0.90380859375}, {"start": 764.07, "end": 765.37, "word": " سالبة", "probability": 0.9303385416666666}], "temperature": 1.0}, {"id": 32, "seek": 78909, "start": 766.73, "end": 789.09, "text": "سالبة ال O minus هنا في ال carbocation الموجب بس احنا راجعنالكم الموضوعين مع بعض حتى تكون عندكم صورة كلية و انا يمكن بقى اعتبر فهم هذا الجزء او هذه الجزئية الصغيرة المتعلقة بالشحنات يعني تقريبا اساس كبير جدا في فهم كل ال organ ال chemistry", "tokens": [3794, 6027, 49401, 2423, 422, 3175, 34105, 8978, 2423, 12143, 27943, 9673, 29245, 3555, 4724, 3794, 1975, 5016, 8315, 12602, 26108, 3615, 8315, 23275, 2304, 9673, 2407, 11242, 45367, 9957, 20449, 45030, 11242, 11331, 49975, 6055, 30544, 43242, 24793, 20328, 13063, 3660, 28242, 10632, 4032, 1975, 8315, 7251, 43020, 4724, 4587, 7578, 1975, 34268, 26890, 6156, 16095, 23758, 25724, 11622, 38207, 1975, 2407, 29538, 25724, 11622, 19986, 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"start": 864.76, "end": 881.82, "text": "طلعوا إيش بيسموه؟ acid طب إيش السبب هنا؟ السبب بالفينول بشكل أساسي هو ال resonance effect إنه لما بيصير عندي هنا شحنة سالبة، بتتنجل هذه الشحنة السالبة وهذا اللي إحنا بنشوفه في ال slide", "tokens": [9566, 1211, 3615, 14407, 11933, 1829, 8592, 4724, 1829, 38251, 2407, 3224, 22807, 8258, 23032, 3555, 11933, 1829, 8592, 21136, 3555, 3555, 34105, 22807, 21136, 3555, 3555, 20666, 5172, 9957, 12610, 4724, 8592, 28820, 5551, 3794, 32277, 1829, 31439, 2423, 30944, 1802, 36145, 3224, 5296, 15042, 4724, 1829, 9381, 13546, 43242, 1829, 34105, 13412, 5016, 1863, 3660, 8608, 6027, 49401, 12399, 39894, 2655, 1863, 7435, 1211, 29538, 25124, 5016, 1863, 3660, 21136, 6027, 49401, 37037, 15730, 13672, 1829, 11933, 5016, 8315, 44945, 8592, 38688, 3224, 8978, 2423, 4137], "avg_logprob": -0.2103230283501443, "compression_ratio": 1.5786802030456852, "no_speech_prob": 2.0265579223632812e-06, "words": [{"start": 864.76, "end": 865.24, "word": "طلعوا", "probability": 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مابتخربش", "probability": 0.846923828125}, {"start": 1162.39, "end": 1163.81, "word": " الملابس،", "probability": 0.914453125}, {"start": 1163.81, "end": 1163.93, "word": " مش", "probability": 0.90380859375}, {"start": 1163.93, "end": 1164.13, "word": " فيها", "probability": 0.973388671875}, {"start": 1164.13, "end": 1165.19, "word": " شيء،", "probability": 0.8396809895833334}, {"start": 1165.19, "end": 1165.35, "word": " بس", "probability": 0.989990234375}, {"start": 1165.35, "end": 1165.49, "word": " ال", "probability": 0.955078125}, {"start": 1165.49, "end": 1165.87, "word": " Bacric", "probability": 0.466064453125}, {"start": 1165.87, "end": 1166.45, "word": " Acid", "probability": 0.757080078125}, {"start": 1166.45, "end": 1167.45, "word": " لأ", "probability": 0.889892578125}, {"start": 1167.45, "end": 1167.97, "word": " بيحرج", "probability": 0.69036865234375}, {"start": 1167.97, "end": 1168.57, "word": " الإيدة", "probability": 0.6652018229166666}], "temperature": 1.0}, {"id": 48, "seek": 120274, "start": 1175.7, "end": 1202.74, "text": "تقريبا هذه أمثلة تأكيدية على الـ electron withdrawing groups لاحظوا هنا بنقول لما يكون عندي تلاتة كلور مثلا مع الاثانول بيكون more acidic than the chloroethanol more acidic than الاثانول itself كل هذا ال effect due to إيش؟ inductive effect زي ما أنتوا شايفينه", "tokens": [2655, 4587, 16572, 3555, 995, 29538, 5551, 2304, 12984, 37977, 6055, 10721, 4117, 25708, 10632, 15844, 2423, 39184, 6084, 14999, 278, 3935, 20193, 5016, 19913, 14407, 34105, 44945, 39648, 5296, 15042, 7251, 30544, 18871, 16254, 6055, 1211, 9307, 3660, 9122, 1211, 13063, 50113, 15040, 20449, 2423, 5718, 104, 7649, 12610, 4724, 1829, 30544, 544, 39514, 813, 264, 18178, 78, 3293, 282, 401, 544, 39514, 813, 2423, 5718, 104, 7649, 12610, 1080, 1967, 28242, 23758, 2423, 1802, 3462, 281, 11933, 1829, 8592, 22807, 31612, 488, 1802, 30767, 1829, 19446, 14739, 2655, 14407, 13412, 995, 33911, 9957, 3224], "avg_logprob": -0.27448453608247425, "compression_ratio": 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بس", "probability": 0.91259765625}, {"start": 1433.53, "end": 1433.71, "word": " مع", "probability": 0.98095703125}, {"start": 1433.71, "end": 1433.87, "word": " ال", "probability": 0.9169921875}, {"start": 1433.87, "end": 1434.15, "word": " sodium", "probability": 0.94970703125}, {"start": 1434.15, "end": 1434.85, "word": " hydroxide", "probability": 0.967529296875}, {"start": 1434.85, "end": 1434.97, "word": " ال", "probability": 0.73486328125}, {"start": 1434.97, "end": 1435.37, "word": " alcohol", "probability": 0.90478515625}, {"start": 1435.37, "end": 1436.41, "word": " مابتفعلش", "probability": 0.8685302734375}], "temperature": 1.0}, {"id": 59, "seek": 146079, "start": 1437.33, "end": 1460.79, "text": "واضح؟ بينما الـ thioalcohols بتعاملوا كأنهم acids RSH زي NAOH حمض زي قاعدة ملح زي دماغ RS minus and A plus هذا الملح زي H2O معدلة الحمض والقاعدة المعروفة عندكم ليس اتفاعل ال RSH مع ال sodium hydroxide", "tokens": [2407, 46958, 5016, 22807, 49374, 15042, 2423, 39184, 258, 1004, 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acidic than ال alcohol فالثيولز، الثيولز بنقول عنهم they react with sodium hydroxide producing salt and water however alcohols they don't react with", "tokens": [10721, 4117, 2655, 2288, 9154, 2423, 9025, 39, 12399, 2423, 9025, 39, 19446, 6055, 5172, 30241, 8592, 20666, 2304, 25720, 21136, 3555, 3555, 14739, 31439, 544, 39514, 813, 2423, 7658, 6156, 6027, 12984, 1829, 12610, 11622, 12399, 2423, 12984, 1829, 12610, 11622, 44945, 39648, 18871, 16095, 436, 4515, 365, 20265, 15435, 34454, 10501, 5139, 293, 1281, 4461, 7658, 82, 436, 500, 380, 4515, 365], "avg_logprob": -0.3752403846153846, "compression_ratio": 1.382198952879581, "no_speech_prob": 4.76837158203125e-07, "words": [{"start": 1462.08, "end": 1462.58, "word": "أكتر", "probability": 0.7640533447265625}, {"start": 1462.58, "end": 1462.78, "word": " من", "probability": 0.986328125}, {"start": 1462.78, "end": 1462.88, "word": " ال", "probability": 0.8857421875}, {"start": 1462.88, "end": 1463.5, "word": " ROH،", "probability": 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