diff --git "a/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/L0JgtlTaovk_raw.json" "b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/L0JgtlTaovk_raw.json"
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+{"segments": [{"id": 1, "seek": 2660, "start": 8.82, "end": 26.6, "text": "إذا بتسمحوا أخر نقطة المرة الماضية اتكلمنا عنها كانت إضافة الماء للالكينز وقولنا إنه في عدة طرق من خلالها بتتم عملية إضافة الماء، الطريقة الأولى", "tokens": [28814, 15730, 39894, 38251, 5016, 14407, 5551, 34740, 8717, 47432, 3660, 9673, 25720, 9673, 46958, 10632, 1975, 2655, 4117, 19528, 8315, 18871, 11296, 25961, 2655, 11933, 11242, 31845, 3660, 9673, 16606, 24976, 6027, 4117, 9957, 11622, 4032, 39648, 8315, 36145, 3224, 8978, 6225, 41891, 23032, 2288, 4587, 9154, 16490, 1211, 6027, 11296, 39894, 39237, 6225, 42213, 10632, 11933, 11242, 31845, 3660, 9673, 16606, 12399, 41950, 16572, 28671, 16247, 12610, 7578], "avg_logprob": -0.1489876777353421, "compression_ratio": 1.7483443708609272, "no_speech_prob": 7.212162017822266e-06, "words": [{"start": 8.82, "end": 9.22, "word": "إذا", "probability": 0.61016845703125}, {"start": 9.22, "end": 9.9, "word": " بتسمحوا", "probability": 0.9608154296875}, {"start": 9.9, 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والحقيقة جميلة جدا لو بدنا نطلع على المثال هذا لو بدنا نطلع على المثال هذا عندكم CH2 CH وهنا CH3 CH3 لو قلنا بدنا نضيف H Plus", "tokens": [3224, 8315, 48127, 2655, 16254, 8315, 13412, 17082, 37977, 11933, 11242, 31845, 10632, 16070, 5016, 38436, 28671, 10874, 2304, 26895, 3660, 10874, 28259, 45164, 47525, 8315, 8717, 9566, 1211, 3615, 15844, 9673, 12984, 6027, 23758, 45164, 47525, 8315, 8717, 9566, 1211, 3615, 15844, 9673, 12984, 6027, 23758, 43242, 24793, 5995, 17, 5995, 4032, 3224, 8315, 5995, 18, 5995, 18, 45164, 12174, 1211, 8315, 47525, 8315, 8717, 11242, 33911, 389, 7721], "avg_logprob": -0.21687939972944661, "compression_ratio": 1.7379310344827585, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 795.27, "end": 795.73, "word": "هنا", "probability": 0.79248046875}, {"start": 795.73, "end": 796.45, "word": " ابتدينا", "probability": 0.706268310546875}, {"start": 796.45, "end": 797.07, "word": " شغلة", "probability": 0.7560221354166666}, {"start": 797.07, "end": 798.35, 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"probability": 0.9921875}, {"start": 807.03, "end": 807.17, "word": " على", "probability": 0.92578125}, {"start": 807.17, "end": 807.55, "word": " المثال", "probability": 0.98388671875}, {"start": 807.55, "end": 807.73, "word": " هذا", "probability": 0.955078125}, {"start": 807.73, "end": 808.11, "word": " عندكم", "probability": 0.89794921875}, {"start": 808.11, "end": 808.71, "word": " CH2", "probability": 0.748779296875}, {"start": 808.71, "end": 809.11, "word": " CH", "probability": 0.5517578125}, {"start": 809.11, "end": 809.89, "word": " وهنا", "probability": 0.6302490234375}, {"start": 809.89, "end": 811.65, "word": " CH3", "probability": 0.7333984375}, {"start": 811.65, "end": 812.55, "word": " CH3", "probability": 0.828125}, {"start": 812.55, "end": 813.09, "word": " لو", "probability": 0.36767578125}, {"start": 813.09, "end": 813.39, "word": " قلنا", "probability": 0.80029296875}, {"start": 813.39, "end": 813.67, "word": " بدنا", "probability": 0.90576171875}, {"start": 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"probability": 0.9619140625}, {"start": 1072.3, "end": 1072.84, "word": " إعادة", "probability": 0.98974609375}, {"start": 1072.84, "end": 1073.82, "word": " الترتيب؟", "probability": 0.8255859375}, {"start": 1073.82, "end": 1075.26, "word": " عشان", "probability": 0.92724609375}, {"start": 1075.26, "end": 1076.08, "word": " أنتقل", "probability": 0.92138671875}, {"start": 1076.08, "end": 1076.48, "word": " من", "probability": 0.9921875}, {"start": 1076.48, "end": 1077.82, "word": " السكندري", "probability": 0.69951171875}, {"start": 1077.82, "end": 1078.28, "word": " كاربو", "probability": 0.80401611328125}, {"start": 1078.28, "end": 1078.9, "word": " كاتايون", "probability": 0.688232421875}, {"start": 1078.9, "end": 1079.36, "word": " إلى", "probability": 0.87548828125}], "temperature": 1.0}, {"id": 49, "seek": 110632, "start": 1080.08, "end": 1106.32, "text": "الـ tertiary carbocation عشان ننتقل من السكندريكاربوكاتيون الى التيرتشاريكاربوكاتيون بتم هنا rearrangement من خلال عملية إيش بنسميها؟ Hydride shift يعني تحرك هيدروجين مع إلكتروناته كلام منطقي ليش؟ لأن هذا موجب الموجب إيش بيكون بده؟ بده سالب إيش السالب؟", "tokens": [6027, 39184, 38726, 29104, 12143, 27943, 6225, 8592, 7649, 8717, 29399, 4587, 1211, 9154, 21136, 19452, 3215, 16572, 4117, 9640, 3555, 2407, 4117, 9307, 1829, 11536, 2423, 7578, 16712, 13546, 2655, 8592, 9640, 1829, 4117, 9640, 3555, 2407, 4117, 9307, 1829, 11536, 4724, 39237, 34105, 39568, 518, 9154, 16490, 1211, 6027, 6225, 42213, 10632, 11933, 1829, 8592, 44945, 38251, 1829, 11296, 22807, 24231, 25502, 5513, 37495, 22653, 6055, 5016, 31747, 8032, 25708, 2288, 29245, 9957, 20449, 11933, 23275, 2655, 2288, 11536, 9307, 3224, 28242, 10943, 9154, 9566, 38436, 32239, 8592, 22807, 5296, 33456, 23758, 3714, 29245, 3555, 9673, 29245, 3555, 11933, 1829, 8592, 4724, 1829, 30544, 47525, 3224, 22807, 47525, 3224, 8608, 6027, 3555, 11933, 1829, 8592, 21136, 6027, 3555, 22807], "avg_logprob": -0.20940061658620834, "compression_ratio": 1.6785714285714286, "no_speech_prob": 9.179115295410156e-06, "words": [{"start": 1080.08, "end": 1080.54, "word": "الـ", "probability": 0.50262451171875}, {"start": 1080.54, "end": 1081.1, "word": " tertiary", "probability": 0.87548828125}, {"start": 1081.1, "end": 1082.26, "word": " carbocation", "probability": 0.82958984375}, {"start": 1082.26, "end": 1083.0, "word": " عشان", "probability": 0.9539388020833334}, {"start": 1083.0, "end": 1083.52, "word": " ننتقل", "probability": 0.98291015625}, {"start": 1083.52, "end": 1083.7, "word": " من", "probability": 0.98779296875}, {"start": 1083.7, "end": 1085.38, "word": " السكندريكاربوكاتيون", "probability": 0.7603352864583334}, {"start": 1085.38, "end": 1085.94, "word": " الى", "probability": 0.71435546875}, {"start": 1085.94, "end": 1087.38, "word": " التيرتشاريكاربوكاتيون", "probability": 0.8760288783482143}, {"start": 1087.38, "end": 1088.16, "word": " بتم", "probability": 0.653564453125}, {"start": 1088.16, "end": 1088.42, "word": " هنا", "probability": 0.10272216796875}, {"start": 1088.42, "end": 1089.36, "word": " rearrangement", "probability": 0.8212890625}, {"start": 1089.36, "end": 1089.54, "word": " من", "probability": 0.99267578125}, {"start": 1089.54, "end": 1089.9, "word": " خلال", "probability": 0.9923502604166666}, {"start": 1089.9, "end": 1090.56, "word": " عملية", "probability": 0.9833984375}, {"start": 1090.56, "end": 1091.04, "word": " إيش", "probability": 0.708740234375}, {"start": 1091.04, "end": 1092.34, "word": " بنسميها؟", "probability": 0.85166015625}, {"start": 1092.34, "end": 1093.94, "word": " Hydride", "probability": 0.4820556640625}, {"start": 1093.94, "end": 1094.42, "word": " shift", "probability": 0.71240234375}, {"start": 1094.42, "end": 1094.8, "word": " يعني", "probability": 0.77587890625}, {"start": 1094.8, "end": 1095.7, "word": " تحرك", "probability": 0.97509765625}, {"start": 1095.7, "end": 1097.06, "word": " هيدروجين", "probability": 0.9234375}, {"start": 1097.06, "end": 1097.28, "word": " مع", "probability": 0.994140625}, {"start": 1097.28, "end": 1098.26, "word": " إلكتروناته", "probability": 0.8846958705357143}, {"start": 1098.26, "end": 1098.9, "word": " كلام", "probability": 0.881103515625}, {"start": 1098.9, "end": 1099.48, "word": " منطقي", "probability": 0.9147135416666666}, {"start": 1099.48, "end": 1100.38, "word": " ليش؟", "probability": 0.760009765625}, {"start": 1100.38, "end": 1100.56, "word": " لأن", "probability": 0.81591796875}, {"start": 1100.56, "end": 1100.96, "word": " هذا", "probability": 0.875}, {"start": 1100.96, "end": 1101.66, "word": " موجب", "probability": 0.96435546875}, {"start": 1101.66, "end": 1102.34, "word": " الموجب", "probability": 0.9007161458333334}, {"start": 1102.34, "end": 1102.52, "word": " إيش", "probability": 0.962890625}, {"start": 1102.52, "end": 1102.8, "word": " بيكون", "probability": 0.9153645833333334}, {"start": 1102.8, "end": 1103.92, "word": " بده؟", "probability": 0.8797200520833334}, {"start": 1103.92, "end": 1104.66, "word": " بده", "probability": 0.91162109375}, {"start": 1104.66, "end": 1105.1, "word": " سالب", "probability": 0.6739908854166666}, {"start": 1105.1, "end": 1105.38, "word": " إيش", "probability": 0.8527018229166666}, {"start": 1105.38, "end": 1106.32, "word": " السالب؟", "probability": 0.95751953125}], "temperature": 1.0}, {"id": 50, "seek": 111424, "start": 1107.2, "end": 1114.24, "text": "الهيدروجين و إلكتروناته هما السالب هما الانيون الهيدروجين مع الإلكترونات تبعته", "tokens": [6027, 3224, 25708, 2288, 29245, 9957, 4032, 11933, 23275, 2655, 2288, 11536, 9307, 3224, 8032, 15042, 21136, 6027, 3555, 8032, 15042, 2423, 7649, 1829, 11536, 2423, 3224, 25708, 2288, 29245, 9957, 20449, 33688, 23275, 2655, 2288, 11536, 9307, 6055, 3555, 34268, 3224], "avg_logprob": -0.24981830702271574, "compression_ratio": 1.6781609195402298, "no_speech_prob": 1.9073486328125e-06, "words": [{"start": 1107.2, "end": 1108.2, "word": "الهيدروجين", "probability": 0.8675130208333334}, {"start": 1108.2, "end": 1108.3, "word": " و", "probability": 0.29248046875}, {"start": 1108.3, "end": 1109.14, "word": " إلكتروناته", "probability": 0.7947998046875}, {"start": 1109.14, "end": 1109.4, "word": " هما", "probability": 0.724609375}, {"start": 1109.4, "end": 1109.96, "word": " السالب", "probability": 0.90380859375}, {"start": 1109.96, "end": 1110.24, "word": " هما", "probability": 0.64892578125}, {"start": 1110.24, "end": 1110.98, "word": " الانيون", "probability": 0.8134765625}, {"start": 1110.98, "end": 1112.2, "word": " الهيدروجين", "probability": 0.9225260416666666}, {"start": 1112.2, "end": 1112.74, "word": " مع", "probability": 0.96630859375}, {"start": 1112.74, "end": 1113.6, "word": " الإلكترونات", "probability": 0.9158528645833334}, {"start": 1113.6, "end": 1114.24, "word": " تبعته", "probability": 0.81787109375}], "temperature": 1.0}, {"id": 51, "seek": 114181, "start": 1118.05, "end": 1141.81, "text": "من مميزات الـ Acid Catalyzed Addition of Water أنه في إمكانية طالما بتكون عندي Carbocation في إمكانية لل rearrangement معنى إمكانية ال rearrangement أنه ممكن ال secondary يصير أحيانا في أمثلة معينة فيها primary برضه ممكن يتحول إلى tertiary واضح؟ هنا عملية ال rearrangement تمت من خلال إيش؟", "tokens": [27842, 3714, 2304, 1829, 11622, 9307, 2423, 39184, 5097, 327, 9565, 5222, 11312, 5349, 849, 295, 8772, 14739, 3224, 8978, 11933, 2304, 41361, 10632, 23032, 6027, 15042, 39894, 30544, 43242, 1829, 2741, 65, 27943, 8978, 11933, 2304, 41361, 10632, 24976, 39568, 518, 20449, 1863, 7578, 11933, 2304, 41361, 10632, 2423, 39568, 518, 14739, 3224, 3714, 43020, 2423, 11396, 7251, 9381, 13546, 5551, 5016, 1829, 7649, 995, 8978, 5551, 2304, 12984, 37977, 20449, 9957, 3660, 8978, 11296, 6194, 4724, 43042, 3224, 3714, 43020, 7251, 2655, 5016, 12610, 30731, 38726, 29104, 4032, 46958, 5016, 22807, 34105, 6225, 42213, 10632, 2423, 39568, 518, 46811, 2655, 9154, 16490, 1211, 6027, 11933, 1829, 8592, 22807], "avg_logprob": -0.17891328748282012, "compression_ratio": 1.67578125, "no_speech_prob": 7.152557373046875e-07, "words": [{"start": 1118.05, "end": 1118.31, "word": "من", "probability": 0.7919921875}, {"start": 1118.31, "end": 1119.33, "word": " مميزات", "probability": 0.9931640625}, {"start": 1119.33, "end": 1119.67, "word": " الـ", "probability": 0.761474609375}, {"start": 1119.67, "end": 1120.13, "word": " Acid", "probability": 0.7249755859375}, {"start": 1120.13, "end": 1120.89, "word": " Catalyzed", "probability": 0.684814453125}, {"start": 1120.89, "end": 1121.39, "word": " Addition", "probability": 0.87744140625}, {"start": 1121.39, "end": 1121.55, "word": " of", "probability": 0.82373046875}, {"start": 1121.55, "end": 1121.97, "word": " Water", "probability": 0.8427734375}, {"start": 1121.97, "end": 1122.33, "word": " أنه", "probability": 0.555419921875}, {"start": 1122.33, "end": 1122.41, "word": " في", "probability": 0.8330078125}, {"start": 1122.41, "end": 1123.25, "word": " إمكانية", "probability": 0.9034423828125}, {"start": 1123.25, "end": 1123.69, "word": " طالما", "probability": 0.9384765625}, {"start": 1123.69, "end": 1124.23, "word": " بتكون", "probability": 0.81298828125}, {"start": 1124.23, "end": 1124.59, "word": " عندي", "probability": 0.47760009765625}, {"start": 1124.59, "end": 1125.19, "word": " Carbocation", "probability": 0.6975911458333334}, {"start": 1125.19, "end": 1125.43, "word": " في", "probability": 0.54345703125}, {"start": 1125.43, "end": 1125.91, "word": " إمكانية", "probability": 0.9754638671875}, {"start": 1125.91, "end": 1126.11, "word": " لل", "probability": 0.67626953125}, {"start": 1126.11, "end": 1126.97, "word": " rearrangement", "probability": 0.6566162109375}, {"start": 1126.97, "end": 1127.55, "word": " معنى", "probability": 0.7649739583333334}, {"start": 1127.55, "end": 1128.07, "word": " إمكانية", "probability": 0.98583984375}, {"start": 1128.07, "end": 1128.25, "word": " ال", "probability": 0.9326171875}, {"start": 1128.25, "end": 1129.01, "word": " rearrangement", "probability": 0.8671875}, {"start": 1129.01, "end": 1129.53, "word": " أنه", "probability": 0.781982421875}, {"start": 1129.53, "end": 1130.23, "word": " ممكن", "probability": 0.9697265625}, {"start": 1130.23, "end": 1130.43, "word": " ال", "probability": 0.67041015625}, {"start": 1130.43, "end": 1130.95, "word": " secondary", "probability": 0.92626953125}, {"start": 1130.95, "end": 1131.51, "word": " يصير", "probability": 0.9718424479166666}, {"start": 1131.51, "end": 1133.05, "word": " أحيانا", "probability": 0.92646484375}, {"start": 1133.05, "end": 1133.21, "word": " في", "probability": 0.7451171875}, {"start": 1133.21, "end": 1133.67, "word": " أمثلة", "probability": 0.9658203125}, {"start": 1133.67, "end": 1134.11, "word": " معينة", "probability": 0.98291015625}, {"start": 1134.11, "end": 1134.39, "word": " فيها", "probability": 0.946044921875}, {"start": 1134.39, "end": 1134.89, "word": " primary", "probability": 0.720703125}, {"start": 1134.89, "end": 1135.23, "word": " برضه", "probability": 0.9339192708333334}, {"start": 1135.23, "end": 1135.53, "word": " ممكن", "probability": 0.9658203125}, {"start": 1135.53, "end": 1136.07, "word": " يتحول", "probability": 0.9925537109375}, {"start": 1136.07, "end": 1136.31, "word": " إلى", "probability": 0.79638671875}, {"start": 1136.31, "end": 1136.95, "word": " tertiary", "probability": 0.958251953125}, {"start": 1136.95, "end": 1138.51, "word": " واضح؟", "probability": 0.67083740234375}, {"start": 1138.51, "end": 1138.91, "word": " هنا", "probability": 0.79833984375}, {"start": 1138.91, "end": 1139.61, "word": " عملية", "probability": 0.9773763020833334}, {"start": 1139.61, "end": 1139.73, "word": " ال", "probability": 0.84521484375}, {"start": 1139.73, "end": 1140.29, "word": " rearrangement", "probability": 0.976806640625}, {"start": 1140.29, "end": 1140.69, "word": " تمت", "probability": 0.99267578125}, {"start": 1140.69, "end": 1140.85, "word": " من", "probability": 0.9970703125}, {"start": 1140.85, "end": 1141.25, "word": " خلال", "probability": 0.9938151041666666}, {"start": 1141.25, "end": 1141.81, "word": " إيش؟", "probability": 0.8111572265625}], "temperature": 1.0}, {"id": 52, "seek": 115669, "start": 1143.61, "end": 1156.69, "text": "الحقيقة اللى لاحظوا انه مش بس من خلال ال hydride shift يعني لو انه بدل ما عندى هنا hydrogen خلتها دول تلاتة methyls لاحظوا المثال السابق هدى إيش كانت؟", "tokens": [6027, 5016, 38436, 28671, 13672, 7578, 20193, 5016, 19913, 14407, 16472, 3224, 37893, 4724, 3794, 9154, 16490, 1211, 6027, 2423, 5796, 25502, 5513, 37495, 22653, 45164, 16472, 3224, 47525, 1211, 19446, 43242, 7578, 34105, 12697, 16490, 1211, 2655, 11296, 11778, 12610, 6055, 1211, 9307, 3660, 36599, 11784, 20193, 5016, 19913, 14407, 9673, 12984, 6027, 21136, 16758, 4587, 8032, 3215, 7578, 11933, 1829, 8592, 25961, 2655, 22807], "avg_logprob": -0.24533582178514396, "compression_ratio": 1.4939024390243902, "no_speech_prob": 7.152557373046875e-07, "words": [{"start": 1143.6100000000001, "end": 1144.45, "word": "الحقيقة", "probability": 0.84356689453125}, {"start": 1144.45, "end": 1144.57, "word": " اللى", "probability": 0.7384033203125}, {"start": 1144.57, "end": 1145.19, "word": " لاحظوا", "probability": 0.81451416015625}, {"start": 1145.19, "end": 1145.75, "word": " انه", "probability": 0.845947265625}, {"start": 1145.75, "end": 1146.13, "word": " مش", "probability": 0.9658203125}, {"start": 1146.13, "end": 1146.71, "word": " بس", "probability": 0.981201171875}, {"start": 1146.71, "end": 1147.27, "word": " من", "probability": 0.99169921875}, {"start": 1147.27, "end": 1147.69, "word": " خلال", "probability": 0.9959309895833334}, {"start": 1147.69, "end": 1147.79, "word": " ال", "probability": 0.978515625}, {"start": 1147.79, "end": 1148.41, "word": " hydride", "probability": 0.5806884765625}, {"start": 1148.41, "end": 1148.81, "word": " shift", "probability": 0.9775390625}, {"start": 1148.81, "end": 1149.51, "word": " يعني", "probability": 0.7392578125}, {"start": 1149.51, "end": 1149.67, 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1235.22, "end": 1236.24, "word": " carbocations", "probability": 0.552001953125}, {"start": 1236.24, "end": 1236.72, "word": " بزام", "probability": 0.81640625}, {"start": 1236.72, "end": 1237.58, "word": " الكربوكاتيونز", "probability": 0.6702880859375}, {"start": 1237.58, "end": 1238.02, "word": " بتسعى", "probability": 0.7803955078125}, {"start": 1238.02, "end": 1238.18, "word": " لل", "probability": 0.464599609375}, {"start": 1238.18, "end": 1238.68, "word": " stability", "probability": 0.6240234375}, {"start": 1238.68, "end": 1239.0, "word": " إذا", "probability": 0.797607421875}, {"start": 1239.0, "end": 1239.18, "word": " في", "probability": 0.389892578125}, {"start": 1239.18, "end": 1239.7, "word": " إمكانية", "probability": 0.90869140625}, {"start": 1239.7, "end": 1240.18, "word": " لإيش", "probability": 0.6824951171875}, {"start": 1240.18, "end": 1240.88, "word": " لل", "probability": 0.31689453125}, {"start": 1240.88, "end": 1242.12, "word": " rearrangement", "probability": 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"probability": 0.981201171875}, {"start": 1249.5, "end": 1249.84, "word": " عندكوا", "probability": 0.8719075520833334}, {"start": 1249.84, "end": 1250.22, "word": " إحساس", "probability": 0.93701171875}, {"start": 1250.22, "end": 1250.36, "word": " أن", "probability": 0.54638671875}, {"start": 1250.36, "end": 1250.86, "word": " أفضل", "probability": 0.964111328125}, {"start": 1250.86, "end": 1251.14, "word": " ناس", "probability": 0.869140625}, {"start": 1251.14, "end": 1251.48, "word": " عندهم", "probability": 0.943603515625}, {"start": 1251.48, "end": 1251.92, "word": " ثبات", "probability": 0.8531901041666666}, {"start": 1251.92, "end": 1252.0, "word": " و", "probability": 0.67236328125}, {"start": 1252.0, "end": 1252.38, "word": " بيشوفوا", "probability": 0.86611328125}, {"start": 1252.38, "end": 1252.72, "word": " كويس", "probability": 0.9777018229166666}, {"start": 1252.72, "end": 1252.86, "word": " اللي", "probability": 0.94921875}, {"start": 1252.86, "end": 1253.3, "word": " قاعدين", "probability": 0.97265625}, {"start": 1253.3, "end": 1253.62, "word": " هنا", "probability": 0.96533203125}, {"start": 1253.62, "end": 1254.98, "word": " واضح؟", "probability": 0.8533935546875}, {"start": 1254.98, "end": 1255.18, "word": " لو", "probability": 0.96337890625}, {"start": 1255.18, "end": 1255.68, "word": " افترضنا", "probability": 0.968359375}, {"start": 1255.68, "end": 1255.82, "word": " أن", "probability": 0.5283203125}, {"start": 1255.82, "end": 1256.14, "word": " الأخت", "probability": 0.886962890625}, {"start": 1256.14, "end": 1256.32, "word": " اللي", "probability": 0.97900390625}, {"start": 1256.32, "end": 1256.62, "word": " هنا", "probability": 0.92724609375}, {"start": 1256.62, "end": 1257.76, "word": " طلعت،", "probability": 0.80047607421875}, {"start": 1257.76, "end": 1258.12, "word": " شو", "probability": 0.90087890625}, {"start": 1258.12, "end": 1258.7, "word": " بيصير؟", "probability": 0.9431640625}], "temperature": 1.0}, {"id": 57, "seek": 128509, "start": 1261.1, "end": 1285.1, "text": "بتناجح عملية ال rearrangement إذا الناس دايما بتسعى نحوها مزيد من الثبات ولا لأ تسعى نحوها مزيد من الثبات الآن بنجي لطريقة تانية غير إضافة الماء في وجود الحامض في طريقة إضافة الماء في وجود الحامض", "tokens": [3555, 2655, 1863, 26108, 5016, 6225, 42213, 10632, 2423, 39568, 518, 11933, 15730, 2423, 8315, 3794, 11778, 47302, 15042, 39894, 3794, 3615, 7578, 8717, 5016, 2407, 11296, 3714, 11622, 25708, 9154, 6024, 104, 3555, 9307, 49429, 5296, 10721, 6055, 3794, 3615, 7578, 8717, 5016, 2407, 11296, 3714, 11622, 25708, 9154, 6024, 104, 3555, 9307, 6024, 48506, 44945, 7435, 1829, 5296, 9566, 16572, 28671, 6055, 7649, 10632, 32771, 13546, 11933, 11242, 31845, 3660, 9673, 16606, 8978, 49610, 23328, 21542, 10943, 11242, 8978, 23032, 16572, 28671, 11933, 11242, 31845, 3660, 9673, 16606, 8978, 49610, 23328, 21542, 10943, 11242], "avg_logprob": -0.16817010309278352, "compression_ratio": 1.9883720930232558, "no_speech_prob": 7.748603820800781e-07, "words": [{"start": 1261.1, "end": 1261.56, "word": "بتناجح", "probability": 0.60478515625}, {"start": 1261.56, "end": 1262.04, "word": " عملية", "probability": 0.876953125}, {"start": 1262.04, "end": 1262.2, "word": " ال", "probability": 0.86181640625}, {"start": 1262.2, "end": 1263.02, "word": " rearrangement", "probability": 0.734375}, {"start": 1263.02, "end": 1263.66, "word": " إذا", "probability": 0.57171630859375}, {"start": 1263.66, "end": 1264.34, "word": " الناس", "probability": 0.96728515625}, {"start": 1264.34, "end": 1264.64, "word": " دايما", "probability": 0.7169596354166666}, {"start": 1264.64, "end": 1265.16, "word": " بتسعى", "probability": 0.9615478515625}, {"start": 1265.16, "end": 1265.5, "word": " نحوها", "probability": 0.8909912109375}, {"start": 1265.5, "end": 1265.88, "word": " مزيد", "probability": 0.9326171875}, {"start": 1265.88, "end": 1266.06, "word": " من", "probability": 0.98828125}, {"start": 1266.06, "end": 1266.58, "word": " الثبات", "probability": 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"probability": 0.965087890625}, {"start": 1277.98, "end": 1278.72, "word": " إضافة", "probability": 0.984619140625}, {"start": 1278.72, "end": 1279.14, "word": " الماء", "probability": 0.971923828125}, {"start": 1279.14, "end": 1279.4, "word": " في", "probability": 0.9853515625}, {"start": 1279.4, "end": 1279.98, "word": " وجود", "probability": 0.96728515625}, {"start": 1279.98, "end": 1280.9, "word": " الحامض", "probability": 0.9822591145833334}, {"start": 1280.9, "end": 1281.52, "word": " في", "probability": 0.71142578125}, {"start": 1281.52, "end": 1282.2, "word": " طريقة", "probability": 0.98681640625}, {"start": 1282.2, "end": 1283.14, "word": " إضافة", "probability": 0.990966796875}, {"start": 1283.14, "end": 1283.72, "word": " الماء", "probability": 0.990966796875}, {"start": 1283.72, "end": 1283.98, "word": " في", "probability": 0.994140625}, {"start": 1283.98, "end": 1284.74, "word": " وجود", "probability": 0.9794921875}, {"start": 1284.74, "end": 1285.1, "word": " الحامض", "probability": 0.88671875}], "temperature": 1.0}, {"id": 58, "seek": 130356, "start": 1285.7, "end": 1303.56, "text": "الزقبق وتحديدا المركب اللي احنا بنستعمله اللي اسمه ال mercuryic acetate mercuryic acetate يعني mercuryic acetate اللي بنسميه احنا ايش خلات الزقبق ال acetic acid حمض", "tokens": [6027, 11622, 4587, 3555, 4587, 34683, 5016, 16254, 28259, 9673, 31747, 3555, 13672, 1829, 1975, 5016, 8315, 44945, 14851, 25957, 43761, 13672, 1829, 24525, 2304, 3224, 2423, 33307, 299, 37848, 473, 33307, 299, 37848, 473, 37495, 22653, 33307, 299, 37848, 473, 13672, 1829, 44945, 38251, 1829, 3224, 1975, 5016, 8315, 1975, 1829, 8592, 16490, 1211, 9307, 6024, 110, 4587, 3555, 4587, 2423, 696, 3532, 8258, 11331, 2304, 11242], "avg_logprob": -0.23437500691068344, "compression_ratio": 1.678082191780822, "no_speech_prob": 8.64267349243164e-06, "words": [{"start": 1285.7, "end": 1286.76, "word": "الزقبق", "probability": 0.769921875}, {"start": 1286.76, "end": 1288.36, "word": " وتحديدا", "probability": 0.77996826171875}, {"start": 1288.36, "end": 1289.14, "word": " المركب", "probability": 0.9348958333333334}, {"start": 1289.14, "end": 1289.32, "word": " اللي", "probability": 0.77734375}, {"start": 1289.32, "end": 1289.6, "word": " احنا", "probability": 0.8243001302083334}, {"start": 1289.6, "end": 1290.6, "word": " بنستعمله", "probability": 0.9742431640625}, {"start": 1290.6, "end": 1291.24, "word": " اللي", "probability": 0.77685546875}, {"start": 1291.24, "end": 1291.64, "word": " اسمه", "probability": 0.9612630208333334}, {"start": 1291.64, "end": 1291.8, "word": " ال", "probability": 0.7119140625}, {"start": 1291.8, "end": 1292.7, "word": " mercuryic", "probability": 0.4560546875}, {"start": 1292.7, "end": 1293.7, "word": " acetate", "probability": 0.838623046875}, {"start": 1293.7, "end": 1294.6, "word": " mercuryic", "probability": 0.6778564453125}, {"start": 1294.6, "end": 1295.2, "word": " acetate", "probability": 0.962646484375}, {"start": 1295.2, "end": 1295.56, "word": " يعني", "probability": 0.74267578125}, {"start": 1295.56, "end": 1296.52, "word": " mercuryic", "probability": 0.6199951171875}, {"start": 1296.52, "end": 1297.02, "word": " acetate", "probability": 0.9501953125}, {"start": 1297.02, "end": 1297.12, "word": " اللي", "probability": 0.960205078125}, {"start": 1297.12, "end": 1297.6, "word": " بنسميه", "probability": 0.898193359375}, {"start": 1297.6, "end": 1297.8, "word": " احنا", "probability": 0.9549153645833334}, {"start": 1297.8, "end": 1298.18, "word": " ايش", "probability": 0.677001953125}, {"start": 1298.18, "end": 1299.44, "word": " خلات", "probability": 0.8502604166666666}, {"start": 1299.44, "end": 1300.7, "word": " الزقبق", "probability": 0.90849609375}, {"start": 1300.7, "end": 1301.4, "word": " ال", "probability": 0.92626953125}, {"start": 1301.4, "end": 1301.94, "word": " acetic", "probability": 0.6363525390625}, {"start": 1301.94, "end": 1302.48, "word": " acid", "probability": 0.97412109375}, {"start": 1302.48, "end": 1303.56, "word": " حمض", "probability": 0.8343098958333334}], "temperature": 1.0}, {"id": 59, "seek": 131516, "start": 1304.42, "end": 1315.16, "text": "الخل .. حمض الخل و ال mercury acetate خلات الزبا .. الآن إذا كان في عندي double bond .. إذا كان في عندي double bond", "tokens": [6027, 9778, 1211, 4386, 11331, 2304, 11242, 33962, 1211, 4032, 2423, 33307, 37848, 473, 16490, 1211, 9307, 6024, 110, 3555, 995, 4386, 6024, 48506, 11933, 15730, 25961, 8978, 43242, 1829, 3834, 6086, 4386, 11933, 15730, 25961, 8978, 43242, 1829, 3834, 6086], "avg_logprob": -0.2686011961528233, "compression_ratio": 1.4434782608695653, "no_speech_prob": 1.1920928955078125e-07, "words": [{"start": 1304.42, "end": 1305.1, "word": "الخل", "probability": 0.9490559895833334}, {"start": 1305.1, "end": 1305.54, "word": " ..", "probability": 0.30712890625}, {"start": 1305.54, "end": 1305.86, "word": " حمض", "probability": 0.8361002604166666}, {"start": 1305.86, "end": 1306.3, "word": " الخل", "probability": 0.983642578125}, {"start": 1306.3, "end": 1306.84, "word": " و", "probability": 0.402587890625}, {"start": 1306.84, "end": 1306.98, "word": " ال", "probability": 0.85693359375}, {"start": 1306.98, "end": 1307.3, "word": " mercury", "probability": 0.42724609375}, {"start": 1307.3, "end": 1308.1, "word": " acetate", "probability": 0.65869140625}, {"start": 1308.1, "end": 1308.54, "word": " خلات", "probability": 0.83984375}, {"start": 1308.54, "end": 1308.98, "word": " الزبا", "probability": 0.840576171875}, {"start": 1308.98, "end": 1309.46, "word": " ..", "probability": 0.68798828125}, {"start": 1309.46, "end": 1310.26, "word": " الآن", "probability": 0.6278076171875}, {"start": 1310.26, "end": 1311.06, "word": " إذا", "probability": 0.7364501953125}, {"start": 1311.06, "end": 1311.38, "word": " كان", "probability": 0.98974609375}, {"start": 1311.38, "end": 1311.58, "word": " في", "probability": 0.93359375}, {"start": 1311.58, "end": 1312.32, "word": " عندي", 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هدولة مع بعض بقالية معينة مش هنتطرق لها حتى ما نتوسعش كتير بضيفوا ميه يعني محصلة هذا ال reagent كله هي عملية إضافة إيش إضافة ميه الآن الميه هنا كيف بتضيف", "tokens": [11242, 33911, 2655, 25894, 11296, 15844, 16490, 9566, 35473, 9957, 44650, 2655, 6027, 36081, 9957, 33962, 9566, 2407, 3660, 16247, 12610, 7578, 3714, 13546, 4117, 13063, 1829, 4117, 5551, 3794, 36081, 36081, 8978, 49610, 23328, 9673, 1829, 3224, 11778, 995, 1829, 3555, 8978, 9673, 1829, 3224, 33962, 9566, 2407, 3660, 16712, 7649, 10632, 3714, 31747, 11703, 3555, 44945, 38251, 1829, 3224, 20265, 14828, 1445, 6655, 25502, 8032, 3215, 12610, 3660, 20449, 45030, 11242, 4724, 4587, 6027, 10632, 20449, 9957, 3660, 37893, 8032, 29399, 9566, 2288, 4587, 5296, 11296, 11331, 49975, 19446, 8717, 2655, 41779, 3615, 8592, 9122, 2655, 13546, 4724, 11242, 33911, 14407, 3714, 1829, 3224, 37495, 22653, 3714, 5016, 36520, 3660, 23758, 2423, 26949, 317, 28242, 3224, 39896, 6225, 42213, 10632, 11933, 11242, 31845, 3660, 11933, 1829, 8592, 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"end": 1482.62, "word": " على", "probability": 0.91796875}, {"start": 1482.62, "end": 1482.92, "word": " أكتر", "probability": 0.90625}, {"start": 1482.92, "end": 1482.98, "word": " و", "probability": 0.89697265625}, {"start": 1482.98, "end": 1483.04, "word": " ال", "probability": 0.88671875}, {"start": 1483.04, "end": 1483.36, "word": " OH", "probability": 0.8681640625}, {"start": 1483.36, "end": 1483.94, "word": " هنا،", "probability": 0.689453125}, {"start": 1483.94, "end": 1484.08, "word": " بده", "probability": 0.8076171875}, {"start": 1484.08, "end": 1484.3, "word": " يطلع", "probability": 0.995361328125}, {"start": 1484.3, "end": 1484.5, "word": " هذا", "probability": 0.97265625}, {"start": 1484.5, "end": 1485.02, "word": " النتج", "probability": 0.8995768229166666}], "temperature": 1.0}, {"id": 67, "seek": 150117, "start": 1487.61, "end": 1501.17, "text": "واضح؟ يعني لو ال reagent اللى عندى mercury acetate بدي يطلع هذا النتج لو ال reagent اللى عندى H plus H2O بدي يطلع هذا النتج شوفت وين الفرق ما بين الشغلتين؟", "tokens": [2407, 46958, 5016, 22807, 37495, 22653, 45164, 2423, 26949, 317, 13672, 7578, 43242, 7578, 33307, 37848, 473, 4724, 16254, 7251, 9566, 1211, 3615, 23758, 28239, 2655, 7435, 45164, 2423, 26949, 317, 13672, 7578, 43242, 7578, 389, 1804, 389, 17, 46, 4724, 16254, 7251, 9566, 1211, 3615, 23758, 28239, 2655, 7435, 13412, 38688, 2655, 4032, 9957, 27188, 2288, 4587, 19446, 49374, 25124, 17082, 1211, 2655, 9957, 22807], "avg_logprob": -0.24440298685387, "compression_ratio": 1.6375838926174497, "no_speech_prob": 4.76837158203125e-07, "words": [{"start": 1487.61, "end": 1488.27, "word": "واضح؟", "probability": 0.640960693359375}, {"start": 1488.27, "end": 1488.57, "word": " يعني", "probability": 0.886474609375}, {"start": 1488.57, "end": 1488.77, "word": " لو", "probability": 0.703125}, {"start": 1488.77, "end": 1488.89, "word": " ال", "probability": 0.94580078125}, {"start": 1488.89, "end": 1489.51, "word": " reagent", "probability": 0.871826171875}, {"start": 1489.51, "end": 1489.73, "word": " اللى", "probability": 0.6927490234375}, {"start": 1489.73, "end": 1490.11, "word": " عندى", "probability": 0.85205078125}, {"start": 1490.11, "end": 1490.47, "word": " mercury", "probability": 0.6103515625}, {"start": 1490.47, "end": 1491.41, "word": " acetate", "probability": 0.6871337890625}, {"start": 1491.41, "end": 1491.91, "word": " بدي", "probability": 0.4825439453125}, {"start": 1491.91, "end": 1492.17, "word": " يطلع", "probability": 0.8812255859375}, {"start": 1492.17, "end": 1492.43, "word": " هذا", "probability": 0.947265625}, {"start": 1492.43, "end": 1492.95, "word": " النتج", "probability": 0.71240234375}, {"start": 1492.95, "end": 1493.35, "word": " لو", "probability": 0.331298828125}, {"start": 1493.35, "end": 1493.49, "word": " ال", "probability": 0.96337890625}, {"start": 1493.49, "end": 1494.05, "word": " reagent", "probability": 0.978515625}, {"start": 1494.05, "end": 1494.27, "word": " اللى", "probability": 0.983154296875}, {"start": 1494.27, "end": 1494.55, "word": " عندى", "probability": 0.79345703125}, {"start": 1494.55, "end": 1494.79, "word": " H", "probability": 0.93408203125}, {"start": 1494.79, "end": 1495.21, "word": " plus", "probability": 0.140869140625}, {"start": 1495.21, "end": 1495.97, "word": " H2O", "probability": 0.6619466145833334}, {"start": 1495.97, "end": 1496.77, "word": " بدي", "probability": 0.950439453125}, {"start": 1496.77, "end": 1497.01, "word": " يطلع", "probability": 0.9840087890625}, {"start": 1497.01, "end": 1497.25, "word": " هذا", "probability": 0.97021484375}, {"start": 1497.25, "end": 1497.81, "word": " النتج", "probability": 0.93896484375}, {"start": 1497.81, "end": 1498.63, "word": " شوفت", "probability": 0.81591796875}, {"start": 1498.63, "end": 1498.87, "word": " وين", "probability": 0.897705078125}, {"start": 1498.87, "end": 1499.47, "word": " الفرق", "probability": 0.9153645833333334}, {"start": 1499.47, "end": 1499.91, "word": " ما", "probability": 0.8603515625}, {"start": 1499.91, "end": 1500.19, "word": " بين", "probability": 0.99267578125}, {"start": 1500.19, "end": 1501.17, "word": " الشغلتين؟", "probability": 0.93505859375}], "temperature": 1.0}, {"id": 68, "seek": 152851, "start": 1502.51, "end": 1528.51, "text": "واضح هذا هو الفرق بين إضافة الميه في وجود حامض إنه فيه إمكانية ل rearrangement إضافة الميه في وجود الذئبق لأ بتضيف حسب Markovnikov rule بدون عملية ال rearrangement عشانك حتى لو بترجع يمكن لل slides لل slides بتلاحظوا في عندنا هنا كلمة إنه ال addition Markovnikov regiochemistry is observed", "tokens": [2407, 46958, 5016, 23758, 31439, 27188, 2288, 4587, 49374, 11933, 11242, 31845, 3660, 9673, 1829, 3224, 8978, 49610, 23328, 11331, 10943, 11242, 36145, 3224, 8978, 3224, 11933, 2304, 41361, 10632, 5296, 39568, 518, 11933, 11242, 31845, 3660, 9673, 1829, 3224, 8978, 49610, 23328, 32545, 19986, 3555, 4587, 5296, 10721, 39894, 11242, 33911, 11331, 35457, 3934, 5179, 13123, 5179, 4978, 47525, 11536, 6225, 42213, 10632, 2423, 39568, 518, 6225, 8592, 7649, 4117, 11331, 49975, 45164, 39894, 47341, 3615, 7251, 43020, 24976, 9788, 24976, 9788, 39894, 15040, 5016, 19913, 14407, 8978, 43242, 8315, 34105, 9122, 19528, 3660, 36145, 3224, 2423, 4500, 3934, 5179, 13123, 5179, 1121, 1004, 48353, 307, 13095], "avg_logprob": -0.1760321029829323, "compression_ratio": 1.6848249027237354, "no_speech_prob": 1.7523765563964844e-05, "words": [{"start": 1502.51, "end": 1502.99, "word": "واضح", "probability": 0.96142578125}, {"start": 1502.99, "end": 1503.69, "word": " هذا", "probability": 0.38232421875}, {"start": 1503.69, "end": 1503.87, "word": " هو", "probability": 0.96240234375}, {"start": 1503.87, "end": 1504.27, "word": " الفرق", "probability": 0.9850260416666666}, {"start": 1504.27, "end": 1504.51, "word": " بين", "probability": 0.8837890625}, {"start": 1504.51, "end": 1505.51, "word": " إضافة", "probability": 0.8829345703125}, {"start": 1505.51, "end": 1505.93, "word": " الميه", "probability": 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"probability": 0.980224609375}, {"start": 1510.51, "end": 1511.15, "word": " الذئبق", "probability": 0.8201904296875}, {"start": 1511.15, "end": 1511.69, "word": " لأ", "probability": 0.823974609375}, {"start": 1511.69, "end": 1512.43, "word": " بتضيف", "probability": 0.8898111979166666}, {"start": 1512.43, "end": 1513.01, "word": " حسب", "probability": 0.96728515625}, {"start": 1513.01, "end": 1513.81, "word": " Markovnikov", "probability": 0.811767578125}, {"start": 1513.81, "end": 1514.45, "word": " rule", "probability": 0.42236328125}, {"start": 1514.45, "end": 1515.37, "word": " بدون", "probability": 0.967041015625}, {"start": 1515.37, "end": 1516.17, "word": " عملية", "probability": 0.9833984375}, {"start": 1516.17, "end": 1517.11, "word": " ال", "probability": 0.64990234375}, {"start": 1517.11, "end": 1517.83, "word": " rearrangement", "probability": 0.951904296875}, {"start": 1517.83, "end": 1518.47, "word": " عشانك", "probability": 0.876708984375}, {"start": 1518.47, "end": 1518.73, "word": " حتى", "probability": 0.8974609375}, {"start": 1518.73, "end": 1518.87, "word": " لو", "probability": 0.9794921875}, {"start": 1518.87, "end": 1519.31, "word": " بترجع", "probability": 0.92724609375}, {"start": 1519.31, "end": 1519.55, "word": " يمكن", "probability": 0.6883544921875}, {"start": 1519.55, "end": 1519.81, "word": " لل", "probability": 0.9365234375}, {"start": 1519.81, "end": 1520.27, "word": " slides", "probability": 0.84765625}, {"start": 1520.27, "end": 1521.53, "word": " لل", "probability": 0.509765625}, {"start": 1521.53, "end": 1522.15, "word": " slides", "probability": 0.94189453125}, {"start": 1522.15, "end": 1522.81, "word": " بتلاحظوا", "probability": 0.9701171875}, {"start": 1522.81, "end": 1522.93, "word": " في", "probability": 0.8193359375}, {"start": 1522.93, "end": 1523.29, "word": " عندنا", "probability": 0.6500244140625}, {"start": 1523.29, "end": 1523.47, "word": " هنا", "probability": 0.7568359375}, {"start": 1523.47, "end": 1524.17, "word": " كلمة", "probability": 0.96337890625}, {"start": 1524.17, "end": 1524.57, "word": " إنه", "probability": 0.58349609375}, {"start": 1524.57, "end": 1524.65, "word": " ال", "probability": 0.8798828125}, {"start": 1524.65, "end": 1525.11, "word": " addition", "probability": 0.93896484375}, {"start": 1525.11, "end": 1526.71, "word": " Markovnikov", "probability": 0.9459228515625}, {"start": 1526.71, "end": 1527.63, "word": " regiochemistry", "probability": 0.721923828125}, {"start": 1527.63, "end": 1527.85, "word": " is", "probability": 0.95263671875}, {"start": 1527.85, "end": 1528.51, "word": " observed", "probability": 0.8828125}], "temperature": 1.0}, {"id": 69, "seek": 155303, "start": 1529.19, "end": 1553.03, "text": "إن الإضافة حسب قاعدة ماركوف نيكوف وهذا ال reaction إيش ماله؟ Rearrangements do not occur إذا لو احنا كنا بنسألكوا سؤال صح و غلط مثلا، بنقولكم in the acid-catalyzed hydration of alkenes, rearrangement is possible", "tokens": [28814, 1863, 33688, 11242, 31845, 3660, 11331, 35457, 12174, 995, 22488, 3660, 3714, 9640, 4117, 38688, 8717, 1829, 4117, 38688, 37037, 15730, 2423, 5480, 11933, 1829, 8592, 3714, 6027, 3224, 22807, 1300, 2284, 933, 1117, 360, 406, 5160, 11933, 15730, 45164, 1975, 5016, 8315, 9122, 8315, 44945, 3794, 10721, 23275, 14407, 8608, 33604, 6027, 20328, 5016, 4032, 32771, 1211, 9566, 50113, 15040, 12399, 44945, 39648, 24793, 294, 264, 8258, 12, 18035, 5222, 11312, 43631, 295, 419, 2653, 279, 11, 39568, 518, 307, 1944], "avg_logprob": -0.27139137791735785, "compression_ratio": 1.353211009174312, "no_speech_prob": 5.960464477539062e-07, "words": [{"start": 1529.19, "end": 1529.47, "word": "إن", "probability": 0.55859375}, {"start": 1529.47, "end": 1529.97, "word": " الإضافة", "probability": 0.89697265625}, {"start": 1529.97, "end": 1530.27, "word": " حسب", "probability": 0.94677734375}, {"start": 1530.27, "end": 1530.79, "word": " قاعدة", "probability": 0.9844970703125}, {"start": 1530.79, "end": 1531.21, "word": " ماركوف", "probability": 0.759307861328125}, {"start": 1531.21, "end": 1531.69, "word": " نيكوف", "probability": 0.8780517578125}, {"start": 1531.69, "end": 1533.09, "word": " وهذا", "probability": 0.5877685546875}, {"start": 1533.09, "end": 1533.23, "word": " ال", "probability": 0.83203125}, {"start": 1533.23, "end": 1533.85, "word": " reaction", "probability": 0.81884765625}, {"start": 1533.85, "end": 1534.71, "word": " إيش", "probability": 0.6577962239583334}, {"start": 1534.71, "end": 1536.33, "word": " ماله؟", "probability": 0.72821044921875}, {"start": 1536.33, "end": 1537.51, "word": " Rearrangements", "probability": 0.66680908203125}, {"start": 1537.51, "end": 1537.75, "word": " do", "probability": 0.7314453125}, {"start": 1537.75, "end": 1537.99, "word": " not", "probability": 0.96630859375}, {"start": 1537.99, "end": 1538.59, "word": " occur", "probability": 0.958984375}, {"start": 1538.59, "end": 1540.25, "word": " إذا", "probability": 0.765625}, {"start": 1540.25, "end": 1540.69, "word": " لو", "probability": 0.79248046875}, {"start": 1540.69, "end": 1540.87, "word": " احنا", "probability": 0.7608235677083334}, {"start": 1540.87, "end": 1541.09, "word": " كنا", "probability": 0.974853515625}, {"start": 1541.09, "end": 1542.01, "word": " بنسألكوا", "probability": 0.86357421875}, {"start": 1542.01, "end": 1542.47, "word": " سؤال", "probability": 0.9890950520833334}, {"start": 1542.47, "end": 1542.75, "word": " صح", "probability": 0.994384765625}, {"start": 1542.75, "end": 1542.87, "word": " و", "probability": 0.95751953125}, {"start": 1542.87, "end": 1543.23, "word": " غلط", "probability": 0.9158528645833334}, {"start": 1543.23, "end": 1544.13, "word": " مثلا،", "probability": 0.7361653645833334}, {"start": 1544.13, "end": 1545.09, "word": " بنقولكم", "probability": 0.7047526041666666}, {"start": 1545.09, "end": 1545.65, "word": " in", "probability": 0.349853515625}, {"start": 1545.65, "end": 1547.77, "word": " the", "probability": 0.79541015625}, {"start": 1547.77, "end": 1548.09, "word": " acid", "probability": 0.953125}, {"start": 1548.09, "end": 1548.81, "word": "-catalyzed", "probability": 0.8087158203125}, {"start": 1548.81, "end": 1549.55, "word": " hydration", "probability": 0.91455078125}, {"start": 1549.55, "end": 1550.35, "word": " of", "probability": 0.95947265625}, {"start": 1550.35, "end": 1551.17, "word": " alkenes,", "probability": 0.8655598958333334}, {"start": 1551.31, "end": 1552.07, "word": " rearrangement", "probability": 0.822509765625}, {"start": 1552.07, "end": 1552.35, "word": " is", "probability": 0.96875}, {"start": 1552.35, "end": 1553.03, "word": " possible", "probability": 0.9619140625}], "temperature": 1.0}, {"id": 70, "seek": 157959, "start": 1555.37, "end": 1579.59, "text": "صح في ال acid catalyzed addition rearrangement is possible in oxymercuration طبعا هذا بنسمي oxymercuration لأنه بضيف الزبق و ال oxygen اللي هي إضافة من خلال الزبق in oxymercuration rearrangement is possible rearrangement does not occur in oxymercuration شفتوا الفرق بين الإضافتين للميه؟", "tokens": [9381, 5016, 8978, 2423, 8258, 3857, 5222, 11312, 4500, 39568, 518, 307, 1944, 294, 5976, 4199, 2869, 8167, 23032, 3555, 3615, 995, 23758, 44945, 38251, 1829, 5976, 4199, 2869, 8167, 5296, 33456, 3224, 4724, 11242, 33911, 6024, 110, 3555, 4587, 4032, 2423, 9169, 13672, 1829, 39896, 11933, 11242, 31845, 3660, 9154, 16490, 1211, 6027, 6024, 110, 3555, 4587, 294, 5976, 4199, 2869, 8167, 39568, 518, 307, 1944, 39568, 518, 775, 406, 5160, 294, 5976, 4199, 2869, 8167, 13412, 5172, 2655, 14407, 27188, 2288, 4587, 49374, 33688, 11242, 31845, 2655, 9957, 5296, 19528, 1829, 3224, 22807], "avg_logprob": -0.1959635402696828, "compression_ratio": 1.6972477064220184, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 1555.37, "end": 1555.87, "word": "صح", "probability": 0.7015380859375}, {"start": 1555.87, "end": 1556.11, "word": " في", "probability": 0.7900390625}, {"start": 1556.11, "end": 1556.21, "word": " ال", 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" هيدروجين", "probability": 0.97763671875}, {"start": 1624.41, "end": 1624.41, "word": " وين", "probability": 0.985107421875}, {"start": 1624.41, "end": 1624.45, "word": " هتيجي", "probability": 0.9481201171875}, {"start": 1624.45, "end": 1624.49, "word": " ال", "probability": 0.98876953125}, {"start": 1624.49, "end": 1624.49, "word": " OH؟", "probability": 0.96533203125}, {"start": 1624.49, "end": 1624.95, "word": " على", "probability": 0.7666015625}, {"start": 1624.95, "end": 1624.95, "word": " هذه", "probability": 0.97021484375}, {"start": 1624.95, "end": 1625.49, "word": " اللي", "probability": 0.9541015625}, {"start": 1625.49, "end": 1625.65, "word": " حاملة", "probability": 0.9894205729166666}, {"start": 1625.65, "end": 1626.09, "word": " هيدروجين", "probability": 0.97919921875}, {"start": 1626.09, "end": 1626.09, "word": " وين", "probability": 0.986328125}, {"start": 1626.09, "end": 1626.09, "word": " هتيجي", "probability": 0.9420166015625}, {"start": 1626.09, "end": 1626.75, "word": " ال", "probability": 0.9873046875}, {"start": 1626.75, "end": 1628.67, "word": " OH؟", "probability": 0.960205078125}, {"start": 1628.67, "end": 1628.83, "word": " على", "probability": 0.7646484375}, {"start": 1628.83, "end": 1629.03, "word": " هذه", "probability": 0.9736328125}, {"start": 1629.03, "end": 1629.37, "word": " اللي", "probability": 0.98583984375}, {"start": 1629.37, "end": 1629.79, "word": " حاملة", "probability": 0.9915364583333334}, {"start": 1629.79, "end": 1630.45, "word": " هيدروجين", "probability": 0.979296875}, {"start": 1630.45, "end": 1631.03, "word": " وين", "probability": 0.986083984375}, {"start": 1631.03, "end": 1631.03, "word": " هتيجي", "probability": 0.9349365234375}, {"start": 1631.03, "end": 1631.03, "word": " ال", "probability": 0.98388671875}, {"start": 1631.03, "end": 1631.69, "word": " OH؟", "probability": 0.953857421875}, {"start": 1631.69, "end": 1631.69, "word": " على", "probability": 0.70361328125}, {"start": 1631.69, "end": 1632.09, "word": " هذه", "probability": 0.97216796875}, {"start": 1632.09, "end": 1633.33, "word": " اللي", "probability": 0.991455078125}, {"start": 1633.33, "end": 1634.13, "word": " حاملة", "probability": 0.9930013020833334}, {"start": 1634.13, "end": 1639.51, "word": " هيدروجين", "probability": 0.9765625}, {"start": 1639.51, "end": 1640.93, "word": " و", "probability": 0.98291015625}], "temperature": 1.0}, {"id": 73, "seek": 165946, "start": 1641.24, "end": 1659.46, "text": "هن بحط ال H و هن بحط ال OH طبعا في هذا المثال الحقيقة مافيش إمكانية برضه ل rearrangement يعني لو كنت هذا المثال تحديدا بدي أكمله في وجود H plus وH to O برضه هيعطي نفس النتجة", "tokens": [3224, 1863, 4724, 5016, 9566, 2423, 389, 4032, 8032, 1863, 4724, 5016, 9566, 2423, 13931, 23032, 3555, 3615, 995, 8978, 23758, 9673, 12984, 6027, 21542, 38436, 28671, 19446, 41185, 8592, 11933, 2304, 41361, 10632, 4724, 43042, 3224, 5296, 39568, 518, 37495, 22653, 45164, 9122, 29399, 23758, 9673, 12984, 6027, 6055, 5016, 16254, 28259, 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"probability": 0.5234375}, {"start": 1643.7, "end": 1646.84, "word": " طبعا", "probability": 0.801513671875}, {"start": 1646.84, "end": 1647.38, "word": " في", "probability": 0.51904296875}, {"start": 1647.38, "end": 1647.72, "word": " هذا", "probability": 0.9228515625}, {"start": 1647.72, "end": 1648.44, "word": " المثال", "probability": 0.97021484375}, {"start": 1648.44, "end": 1649.32, "word": " الحقيقة", "probability": 0.9541015625}, {"start": 1649.32, "end": 1649.74, "word": " مافيش", "probability": 0.8766276041666666}, {"start": 1649.74, "end": 1650.32, "word": " إمكانية", "probability": 0.8680419921875}, {"start": 1650.32, "end": 1650.64, "word": " برضه", "probability": 0.7794596354166666}, {"start": 1650.64, "end": 1650.76, "word": " ل", "probability": 0.91796875}, {"start": 1650.76, "end": 1651.56, "word": " rearrangement", "probability": 0.762451171875}, {"start": 1651.56, "end": 1651.72, "word": " يعني", "probability": 0.6500244140625}, {"start": 1651.72, "end": 1651.86, "word": " لو", "probability": 0.96142578125}, {"start": 1651.86, "end": 1652.04, "word": " كنت", "probability": 0.982177734375}, {"start": 1652.04, "end": 1652.32, "word": " هذا", "probability": 0.9072265625}, {"start": 1652.32, "end": 1652.82, "word": " المثال", "probability": 0.9847005208333334}, {"start": 1652.82, "end": 1653.58, "word": " تحديدا", "probability": 0.92138671875}, {"start": 1653.58, "end": 1654.12, "word": " بدي", "probability": 0.650146484375}, {"start": 1654.12, "end": 1654.64, "word": " أكمله", "probability": 0.9270833333333334}, {"start": 1654.64, "end": 1654.82, "word": " في", "probability": 0.95361328125}, {"start": 1654.82, "end": 1655.24, "word": " وجود", "probability": 0.963134765625}, {"start": 1655.24, "end": 1655.52, "word": " H", "probability": 0.93212890625}, {"start": 1655.52, "end": 1656.08, "word": " plus", "probability": 0.2099609375}, {"start": 1656.08, "end": 1657.3, "word": " وH", "probability": 0.70947265625}, {"start": 1657.3, "end": 1657.54, "word": " to", "probability": 0.52197265625}, {"start": 1657.54, "end": 1657.68, "word": " O", "probability": 0.9345703125}, {"start": 1657.68, "end": 1657.98, "word": " برضه", "probability": 0.9539388020833334}, {"start": 1657.98, "end": 1658.38, "word": " هيعطي", "probability": 0.8836669921875}, {"start": 1658.38, "end": 1658.6, "word": " نفس", "probability": 0.998291015625}, {"start": 1658.6, "end": 1659.46, "word": " النتجة", "probability": 0.7899169921875}], "temperature": 1.0}, {"id": 74, "seek": 168259, "start": 1660.25, "end": 1682.59, "text": "يعني احنا دايما بنقول ان ال rearrangement possible بس مش دايما ممكن ال rearrangement يعني لما يكون فيه امكانية انه اي carbocation يتحسن لاشي افضل بيصير طب لو مافيش امكانية مابصيرش يعني لو على هذا المثال انا كنت بده اضيف H plus H2O الخطوة الأولى شو هتكون؟", "tokens": [40228, 22653, 1975, 5016, 8315, 11778, 47302, 15042, 44945, 39648, 16472, 2423, 39568, 518, 1944, 4724, 3794, 37893, 11778, 47302, 15042, 3714, 43020, 2423, 39568, 518, 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{"start": 1661.51, "end": 1661.69, "word": " ان", "probability": 0.82568359375}, {"start": 1661.69, "end": 1661.81, "word": " ال", "probability": 0.73876953125}, {"start": 1661.81, "end": 1662.69, "word": " rearrangement", "probability": 0.77587890625}, {"start": 1662.69, "end": 1663.35, "word": " possible", "probability": 0.88720703125}, {"start": 1663.35, "end": 1664.11, "word": " بس", "probability": 0.841064453125}, {"start": 1664.11, "end": 1664.33, "word": " مش", "probability": 0.97509765625}, {"start": 1664.33, "end": 1664.83, "word": " دايما", "probability": 0.857421875}, {"start": 1664.83, "end": 1665.35, "word": " ممكن", "probability": 0.990478515625}, {"start": 1665.35, "end": 1665.51, "word": " ال", "probability": 0.75830078125}, {"start": 1665.51, "end": 1666.23, "word": " rearrangement", "probability": 0.9580078125}, {"start": 1666.23, "end": 1666.35, "word": " يعني", "probability": 0.77294921875}, {"start": 1666.35, "end": 1666.55, "word": " لما", "probability": 0.9345703125}, {"start": 1666.55, "end": 1666.83, "word": " يكون", "probability": 0.978759765625}, {"start": 1666.83, "end": 1667.09, "word": " فيه", "probability": 0.65966796875}, {"start": 1667.09, "end": 1667.79, "word": " امكانية", "probability": 0.7840576171875}, {"start": 1667.79, "end": 1668.77, "word": " انه", "probability": 0.70166015625}, {"start": 1668.77, "end": 1669.07, "word": " اي", "probability": 0.89208984375}, {"start": 1669.07, "end": 1669.97, "word": " carbocation", "probability": 0.51470947265625}, {"start": 1669.97, "end": 1670.75, "word": " يتحسن", "probability": 0.99033203125}, {"start": 1670.75, "end": 1671.09, "word": " لاشي", "probability": 0.7394205729166666}, {"start": 1671.09, "end": 1671.45, "word": " افضل", "probability": 0.9317626953125}, {"start": 1671.45, "end": 1671.85, "word": " بيصير", "probability": 0.9439697265625}, {"start": 1671.85, "end": 1672.05, "word": " طب", "probability": 0.81884765625}, {"start": 1672.05, "end": 1672.17, "word": " لو", 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"probability": 0.95849609375}, {"start": 1677.83, "end": 1678.75, "word": " H", "probability": 0.890625}, {"start": 1678.75, "end": 1679.47, "word": " plus", "probability": 0.10595703125}, {"start": 1679.47, "end": 1680.75, "word": " H2O", "probability": 0.81494140625}, {"start": 1680.75, "end": 1681.53, "word": " الخطوة", "probability": 0.95654296875}, {"start": 1681.53, "end": 1681.87, "word": " الأولى", "probability": 0.8961588541666666}, {"start": 1681.87, "end": 1682.01, "word": " شو", "probability": 0.87646484375}, {"start": 1682.01, "end": 1682.59, "word": " هتكون؟", "probability": 0.907470703125}], "temperature": 1.0}, {"id": 75, "seek": 170976, "start": 1684.42, "end": 1709.76, "text": "إضافة الـ H plus تخيلوا إضافت هنا صار Carbocation هنا شو نوع هذا Carbocation؟ طيب tertiary هيعمل rearrangement؟ في أحسن من ال tertiary؟ بناء على ذلك ه��كمل بدون rearrangement وبالتالي في هذا المثال تحديدًا في هذا المثال تحديدًا بأي شكل من الأشكال ضفت أنا", "tokens": [28814, 11242, 31845, 3660, 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الموقع", "probability": 0.9695638020833334}, {"start": 1805.83, "end": 1806.43, "word": " السكندري", "probability": 0.70166015625}, {"start": 1806.43, "end": 1807.09, "word": " بينقل", "probability": 0.79107666015625}, {"start": 1807.09, "end": 1811.79, "word": " هاي", "probability": 0.409912109375}, {"start": 1811.79, "end": 1812.33, "word": " الناتج", "probability": 0.6936848958333334}, {"start": 1812.33, "end": 1813.71, "word": " شوفتوا", "probability": 0.7166748046875}, {"start": 1813.71, "end": 1814.05, "word": " الفرق", "probability": 0.98095703125}, {"start": 1814.05, "end": 1814.29, "word": " بين", "probability": 0.97216796875}, {"start": 1814.29, "end": 1815.35, "word": " الطريقتين؟", "probability": 0.94638671875}], "temperature": 1.0}, {"id": 80, "seek": 184110, "start": 1816.66, "end": 1841.1, "text": "إذا في هذا المثال يختلف عندي إذا أضيف الميه باستعمال الحامض أو باستعمال الذئبق باستعمال الذئبق لا يوجد نقاش أتيت ال H هنا و ال O هنا التفاعل هذا لا يوجد فيه rearrangement على الطرفين الرامض لا يوجد rearrangement في وجود الحامض أول ما تأتي ال H هنا و تعمل positive", "tokens": [28814, 15730, 8978, 23758, 9673, 12984, 6027, 7251, 46456, 46538, 18871, 16254, 11933, 15730, 5551, 11242, 33911, 9673, 1829, 3224, 4724, 995, 14851, 25957, 6027, 21542, 10943, 11242, 34051, 4724, 995, 14851, 25957, 6027, 32545, 19986, 3555, 4587, 4724, 995, 14851, 25957, 6027, 32545, 19986, 3555, 4587, 20193, 7251, 29245, 3215, 8717, 4587, 33599, 5551, 31371, 2655, 2423, 389, 34105, 4032, 2423, 422, 34105, 16712, 5172, 995, 30241, 23758, 20193, 7251, 29245, 3215, 8978, 3224, 39568, 518, 15844, 41950, 28480, 9957, 34892, 10943, 11242, 20193, 7251, 29245, 3215, 39568, 518, 8978, 49610, 23328, 21542, 10943, 11242, 5551, 12610, 19446, 6055, 10721, 31371, 2423, 389, 34105, 4032, 6055, 25957, 1211, 3353], "avg_logprob": -0.27547859930777335, "compression_ratio": 2.0514018691588785, "no_speech_prob": 1.1920928955078125e-07, "words": [{"start": 1816.66, "end": 1816.94, "word": "إذا", 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{"start": 1835.74, "end": 1835.82, "word": " لا", "probability": 0.4833984375}, {"start": 1835.82, "end": 1835.98, "word": " يوجد", "probability": 0.8771158854166666}, {"start": 1835.98, "end": 1836.72, "word": " rearrangement", "probability": 0.9482421875}, {"start": 1836.72, "end": 1837.2, "word": " في", "probability": 0.900390625}, {"start": 1837.2, "end": 1837.7, "word": " وجود", "probability": 0.936279296875}, {"start": 1837.7, "end": 1838.44, "word": " الحامض", "probability": 0.9921875}, {"start": 1838.44, "end": 1838.98, "word": " أول", "probability": 0.93212890625}, {"start": 1838.98, "end": 1839.12, "word": " ما", "probability": 0.916015625}, {"start": 1839.12, "end": 1839.46, "word": " تأتي", "probability": 0.8229166666666666}, {"start": 1839.46, "end": 1839.6, "word": " ال", "probability": 0.84619140625}, {"start": 1839.6, "end": 1839.88, "word": " H", "probability": 0.93505859375}, {"start": 1839.88, "end": 1840.2, "word": " هنا", "probability": 0.931640625}, {"start": 1840.2, "end": 1840.34, "word": " و", "probability": 0.6328125}, {"start": 1840.34, "end": 1840.7, "word": " تعمل", "probability": 0.96533203125}, {"start": 1840.7, "end": 1841.1, "word": " positive", "probability": 0.84765625}], "temperature": 1.0}, {"id": 81, "seek": 187195, "start": 1843.07, "end": 1871.95, "text": "شو بيصير عندى؟ بيصير عندى الـ hydrate shift rearrangement الـ positive بيصير على هذا الموقع و الـ OH بتيجي على هذا الموقع إذا هنا الناتج مختلف تماما ولا لأ؟ أه فوجود طريقتين، الطريقتين لا يعطوا نفس الناتج مرات بيعطوا إذا مافيش إمكانية لل rearrangement لكن لو في إمكانية لل rearrangement ال rearrangement بتصير في وجود الحامض مابتصيرش في وجود الذئبق", "tokens": [8592, 2407, 4724, 1829, 9381, 13546, 43242, 7578, 22807, 4724, 1829, 9381, 13546, 43242, 7578, 2423, 39184, 5796, 4404, 5513, 39568, 518, 2423, 39184, 3353, 4724, 1829, 9381, 13546, 15844, 23758, 9673, 30543, 3615, 4032, 2423, 39184, 13931, 39894, 1829, 7435, 1829, 15844, 23758, 9673, 30543, 3615, 11933, 15730, 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"seek": 223812, "start": 2208.9, "end": 2238.12, "text": "نقص إلكترونات الوضع الطبيعي كم حول الذر يكون عنده إلكترونات 8 أربع روابط الآن هنا البرون في هذا الجزء ال بي اتش تري كم أصلا حواليه ستة إذا هو electron acceptor بده إلكترونات والإلكترون acceptor حسب تعريف الحمض والقاعدة حسب Lewis Definition اتذكروا تعريف Lewis للحمض والقاعدة ال acid is electron", "tokens": [1863, 4587, 9381, 11933, 23275, 2655, 2288, 11536, 9307, 2423, 2407, 11242, 3615, 41950, 21292, 3615, 1829, 9122, 2304, 11331, 12610, 32545, 2288, 7251, 30544, 43242, 3224, 11933, 23275, 2655, 2288, 11536, 9307, 1649, 5551, 25513, 3615, 12602, 14407, 3555, 9566, 6024, 48506, 34105, 2423, 26890, 11536, 8978, 23758, 25724, 11622, 38207, 2423, 4724, 1829, 1975, 2655, 8592, 6055, 16572, 9122, 2304, 5551, 9381, 15040, 11331, 2407, 6027, 1829, 3224, 8608, 2655, 3660, 11933, 15730, 31439, 6084, 3241, 284, 47525, 3224, 11933, 23275, 2655, 2288, 11536, 9307, 16070, 28814, 23275, 2655, 2288, 11536, 3241, 284, 11331, 35457, 37279, 16572, 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H", "probability": 0.6181640625}, {"start": 2305.9, "end": 2306.16, "word": " مع", "probability": 0.9892578125}, {"start": 2306.16, "end": 2307.26, "word": " إلكتروناتها", "probability": 0.8669782366071429}, {"start": 2307.26, "end": 2308.16, "word": " بالضيف", "probability": 0.8701171875}, {"start": 2308.16, "end": 2308.7, "word": " إذا", "probability": 0.7158203125}, {"start": 2308.7, "end": 2309.08, "word": " هنا", "probability": 0.94873046875}, {"start": 2309.08, "end": 2309.42, "word": " في", "probability": 0.90185546875}, {"start": 2309.42, "end": 2309.84, "word": " الخطوة", "probability": 0.9755859375}, {"start": 2309.84, "end": 2310.18, "word": " الأولى", "probability": 0.9939778645833334}, {"start": 2310.18, "end": 2310.5, "word": " بيصير", "probability": 0.913330078125}, {"start": 2310.5, "end": 2310.96, "word": " عندك", "probability": 0.580322265625}, {"start": 2310.96, "end": 2311.4, "word": " H", "probability": 0.86669921875}, {"start": 2311.4, "end": 2312.48, "word": " و", "probability": 0.82177734375}, {"start": 2312.48, "end": 2313.4, "word": " BH2", "probability": 0.7158203125}, {"start": 2313.4, "end": 2314.44, "word": " هدولة", "probability": 0.81396484375}, {"start": 2314.44, "end": 2314.6, "word": " اللي", "probability": 0.9345703125}, {"start": 2314.6, "end": 2315.12, "word": " ضافوا", "probability": 0.892578125}], "temperature": 1.0}, {"id": 100, "seek": 233782, "start": 2315.82, "end": 2337.82, "text": "واضح؟ فعدك مجرد ما تحط ال H2O2 و ال hydrogen peroxide مكان ال BH2 ال hydrogen peroxide بتطرد ال BH2 بتحط محلها OH الان لاحظوا معي وين إجت ال H على اللي حمل ال hydrogen أكتر ولا أقل حسب Markovnikov", "tokens": [2407, 46958, 5016, 22807, 6156, 22488, 4117, 3714, 7435, 2288, 3215, 19446, 6055, 5016, 9566, 2423, 389, 17, 46, 17, 4032, 2423, 12697, 4768, 34454, 3714, 41361, 2423, 40342, 17, 2423, 12697, 4768, 34454, 39894, 9566, 2288, 3215, 2423, 40342, 17, 39894, 5016, 9566, 3714, 5016, 1211, 11296, 13931, 2423, 7649, 20193, 5016, 19913, 14407, 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