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56.639461517333984 46 WikiText2
1950 Organoantimony compounds are typically prepared by alkylation of antimony halides with Grignard reagents . A large variety of compounds are known with both Sb ( III ) and Sb ( V ) centers , including mixed chloro @-@ organic derivatives , anions , and cations . Examples include Sb ( C6H5 ) 3 ( triphenylstibine ) , Sb2 ( C6H5 ) 4 ( with an Sb @-@ Sb bond ) , and cyclic [ Sb ( C6H5 ) ] n . Pentacoordinated organoantimony compounds are common , examples being Sb ( C6H5 ) 5 and several related halides .
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1951 = = History = =
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1952 Antimony ( III ) sulfide , Sb2S3 , was recognized in predynastic Egypt as an eye cosmetic ( kohl ) as early as about 3100 BC , when the cosmetic palette was invented .
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1953 An artifact , said to be part of a vase , made of antimony dating to about 3000 BC was found at Telloh , Chaldea ( part of present @-@ day Iraq ) , and a copper object plated with antimony dating between 2500 BC and 2200 BC has been found in Egypt . Austen , at a lecture by Herbert Gladstone in 1892 commented that " we only know of antimony at the present day as a highly brittle and crystalline metal , which could hardly be fashioned into a useful vase , and therefore this remarkable ' find ' ( artifact mentioned above ) must represent the lost art of rendering antimony malleable . "
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1954 Moorey was unconvinced the artifact was indeed a vase , mentioning that Selimkhanov , after his analysis of the Tello object ( published in 1975 ) , " attempted to relate the metal to Transcaucasian natural antimony " ( i.e. native metal ) and that " the antimony objects from Transcaucasia are all small personal ornaments . " This weakens the evidence for a lost art " of rendering antimony malleable . "
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1955 The Roman scholar Pliny the Elder described several ways of preparing antimony sulfide for medical purposes in his treatise Natural History . Pliny the Elder also made a distinction between " male " and " female " forms of antimony ; the male form is probably the sulfide , while the female form , which is superior , heavier , and less friable , has been suspected to be native metallic antimony .
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1956 The Roman naturalist Pedanius Dioscorides mentioned that antimony sulfide could be roasted by heating by a current of air . It is thought that this produced metallic antimony .
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1957 The first description of a procedure for isolating antimony is in the book De la pirotechnia of 1540 by Vannoccio Biringuccio ; this predates the more famous 1556 book by Agricola , De re metallica . In this context Agricola has been often incorrectly credited with the discovery of metallic antimony . The book Currus Triumphalis Antimonii ( The Triumphal Chariot of Antimony ) , describing the preparation of metallic antimony , was published in Germany in 1604 . It was purported to have been written by a Benedictine monk , writing under the name Basilius Valentinus , in the 15th century ; if it were authentic , which it is not , it would predate Biringuccio .
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1958 The metal antimony was known to German chemist Andreas Libavius in 1615 who obtained it by adding iron to a molten mixture of antimony sulfide , salt and potassium tartrate . This procedure produced antimony with a crystalline or starred surface .
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1959 With the advent of challenges to phlogiston theory it was recognized that antimony is an element forming sulfides , oxides , and other compounds , as is the case with other metals .
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1960 The first natural occurrence of pure antimony in the Earth 's crust was described by the Swedish scientist and local mine district engineer Anton von Swab in 1783 ; the type @-@ sample was collected from the Sala Silver Mine in the Bergslagen mining district of Sala , Västmanland , Sweden .
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1961 = = = Etymology = = =
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1962 The ancient words for antimony mostly have , as their chief meaning , kohl , the sulfide of antimony .
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1963 The Egyptians called antimony mśdmt ; in hieroglyphs , the vowels are uncertain , but there is an Arabic tradition that the word is ميسديميت mesdemet . The Greek word , στίμμι stimmi , is probably a loan word from Arabic or from Egyptian stm
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1964 and is used by Attic tragic poets of the 5th century BC ; later Greeks also used στἰβι stibi , as did Celsus and Pliny , writing in Latin , in the first century AD . Pliny also gives the names stimi [ sic ] , larbaris , alabaster , and the " very common " platyophthalmos , " wide @-@ eye " ( from the effect of the cosmetic ) . Later Latin authors adapted the word to Latin as stibium . The Arabic word for the substance , as opposed to the cosmetic , can appear as إثمد ithmid , athmoud , othmod , or uthmod . Littré suggests the first form , which is the earliest , derives from stimmida , an accusative for stimmi .
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1965 The use of Sb as the standard chemical symbol for antimony is due to Jöns Jakob Berzelius , who used this abbreviation of the name stibium . The medieval Latin form , from which the modern languages and late Byzantine Greek take their names for antimony , is antimonium . The origin of this is uncertain ; all suggestions have some difficulty either of form or interpretation . The popular etymology , from ἀντίμοναχός anti @-@ monachos or French antimoine , still has adherents ; this would mean " monk @-@ killer " , and is explained by many early alchemists being monks , and antimony being poisonous .
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1966 Another popular etymology is the hypothetical Greek word ἀντίμόνος antimonos , " against aloneness " , explained as " not found as metal " , or " not found unalloyed " . Lippmann conjectured a hypothetical Greek word ανθήμόνιον anthemonion , which would mean " floret " , and cites several examples of related Greek words ( but not that one ) which describe chemical or biological efflorescence .
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1967 The early uses of antimonium include the translations , in 1050 – 1100 , by Constantine the African of Arabic medical treatises . Several authorities believe antimonium is a scribal corruption of some Arabic form ; Meyerhof derives it from ithmid ; other possibilities include athimar , the Arabic name of the metalloid , and a hypothetical as @-@ stimmi , derived from or parallel to the Greek .
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1968 = = Production = =
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1969 = = = Top producers and production volumes = = =
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1970 The British Geological Survey ( BGS ) reported that in 2005 , China was the top producer of antimony with an approximately 84 % world share , followed at a distance by South Africa , Bolivia and Tajikistan . Xikuangshan Mine in Hunan province has the largest deposits in China with an estimated deposit of 2 @.@ 1 million metric tons .
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1971 In 2010 , according to the US Geological Survey , China accounted for 88 @.@ 9 % of total antimony production with South Africa , Bolivia and Russia sharing the second place .
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1972 However , Roskill Consulting estimates for primary production show that in 2010 China held a 76 @.@ 75 % share of world supply with 120 @,@ 462 tonnes ( 90 @,@ 000 tonnes of reported and 30 @,@ 464 tonnes of un @-@ reported production ) , followed by Russia ( 4 @.@ 14 % share , 6 @,@ 500 tonnes of production ) , Myanmar ( 3 @.@ 76 % share , 5 @,@ 897 tonnes ) , Canada ( 3 @.@ 61 % share , 5 @,@ 660 tonnes ) , Tajikistan ( 3 @.@ 42 % share , 5 @,@ 370 tonnes ) and Bolivia ( 3 @.@ 17 % share , 4 @,@ 980 tonnes ) .
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1973 Roskill estimates that secondary production globally in 2010 was 39 @,@ 540 tonnes .
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1974 Antimony was ranked first in a Risk List published by the British Geological Survey in the second half of 2011 . The list provides an indication of the relative risk to the supply of chemical elements or element groups required to maintain the current British economy and lifestyle .
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1975 Also , antimony was identified as one of 12 critical raw materials for the EU in a report published in 2011 , primarily due to the lack of supply outside China .
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1976 Reported production of antimony in China fell in 2010 and is unlikely to increase in the coming years , according to the Roskill report . No significant antimony deposits in China have been developed for about ten years , and the remaining economic reserves are being rapidly depleted .
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1977 The world 's largest antimony producers , according to Roskill , are listed below :
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1978 = = = Reserves = = =
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1979 According to statistics from the USGS , current global reserves of antimony will be depleted in 13 years . However , the USGS expects more resources will be found .
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1980 = = = Production process = = =
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1981 The extraction of antimony from ores depends on the quality of the ore and composition of the ore . Most antimony is mined as the sulfide ; lower @-@ grade ores are concentrated by froth flotation , while higher @-@ grade ores are heated to 500 – 600 ° C , the temperature at which stibnite melts and is separated from the gangue minerals . Antimony can be isolated from the crude antimony sulfide by a reduction with scrap iron :
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1982 Sb
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1983 2S
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1984 3 + 3 Fe → 2 Sb + 3 FeS
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1985 The sulfide is converted to an oxide and advantage is often taken of the volatility of antimony ( III ) oxide , which is recovered from roasting . This material is often used directly for the main applications , impurities being arsenic and sulfide . Isolating antimony from its oxide is performed by a carbothermal reduction :
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1986 2 Sb
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1987 2O
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1988 3 + 3 C → 4 Sb + 3 CO
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1989 2
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1990 The lower @-@ grade ores are reduced in blast furnaces while the higher @-@ grade ores are reduced in reverberatory furnaces .
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1991 = = Applications = =
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1992 About 60 % of antimony is consumed in flame retardants , and 20 % is used in alloys for batteries , plain bearings and solders .
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1993 = = = Flame retardants = = =
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1994 Antimony is mainly used as its trioxide in making flame @-@ proofing compounds . It is nearly always used in combination with halogenated flame retardants , with the only exception being in halogen @-@ containing polymers . The formation of halogenated antimony compounds is the cause for the flame retarding effect of antimony trioxide , due to reaction of these compounds with hydrogen atoms and probably also with oxygen atoms and OH radicals , thus inhibiting fire . Markets for these flame @-@ retardant applications include children 's clothing , toys , aircraft and automobile seat covers . It is also used in the fiberglass composites industry as an additive to polyester resins for such items as light aircraft engine covers . The resin will burn while a flame is held to it but will extinguish itself as soon as the flame is removed .
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1995 = = = Alloys = = =
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1996 Antimony forms a highly useful alloy with lead , increasing its hardness and mechanical strength . For most applications involving lead , varying amounts of antimony are used as alloying metal . In lead – acid batteries , this addition improves the charging characteristics and reduces generation of unwanted hydrogen during charging . It is used in antifriction alloys ( such as Babbitt metal ) , in bullets and lead shot , cable sheathing , type metal ( for example , for linotype printing machines ) , solder ( some " lead @-@ free " solders contain 5 % Sb ) , in pewter , and in hardening alloys with low tin content in the manufacturing of organ pipes .
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1997 = = = Other applications = = =
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1998 Three other applications make up nearly all the rest of the consumption . One of these uses is as a stabilizer and a catalyst for the production of polyethyleneterephthalate . Another application is to serve as a fining agent to remove microscopic bubbles in glass , mostly for TV screens ; this is achieved by the interaction of antimony ions with oxygen , interfering the latter from forming bubbles . The third major application is the use as pigment .
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1999 Antimony is being increasingly used in the semiconductor industry as a dopant for heavily doped n @-@ type silicon wafers in the production of diodes , infrared detectors , and Hall @-@ effect devices . In the 1950s , tiny beads of a lead @-@ antimony alloy were used to dope the emitters and collectors of n @-@ p @-@ n alloy junction transistors with antimony . Indium antimonide is used as a material for mid @-@ infrared detectors .